Recent advances for the photoinduced C—C bond cleavage of cycloketone oximes  

作　　者：Wei Xiao Jie Wu 

机构地区：[1]School of Pharmaceutical and Materials Engineering&Institute for Advanced Studies,Taizhou University,Taizhou 318000,China [2]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

出　　处：《Chinese Chemical Letters》2020年第12期3083-3094,共12页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China(Nos.21672037 and 21532001);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(No.2019R01005)。

摘　　要：Nitriles are widely existed in many bioactive compounds,and they can be easily transformed into other functional groups.Therefore,the synthesis of nitriles under cyanide-free conditions is of significant importance.Recent advances for the synthesis of nitriles through photoinduced C—C bond cleavage of cycloketone oximes classified by the type of C—X bond forming are summarized.Various compounds possessing nitriles can be efficiently accessed via this method.

关 键 词：NITRILES C—C bond cleavage Cycloketone oximes RADICAL PHOTOCATALYSIS 

分 类 号：TQ226.61[化学工程—有机化工]