Transition Metal Catalyzed Enantioselective Borylative Cyclization Reactions  

作　　者：Yuqi Ji Min Zhang Mimi Xing Huanhuan Cui Qian Zhao Chun Zhang 

机构地区：[1]Institute of Molecular Plus,Tianjin Key Laboratory of Molecular Optoelectronic Science,Department of Chemistry,School of Science,Tianjin University,Weijin Rd.92,Tianjin,300072 China

出　　处：《Chinese Journal of Chemistry》2021年第2期391-401,共11页中国化学（英文版）

基　　金：Financial support from Tianjin University and the National Natural Science Foundation of China(No.21801181)is acknowledged.

摘　　要：Due to the significance of corresponding products,enantioselective borylative cyclization reactions have been studied intensively in recent years.Many groups have developed efficient methods to transform unsaturated system into asymmetric cyclic organoboron compounds with the ring-size range from three-membered to six-membered in general.Notably,in some cases,fused rings which contain more than two contiguous chiral centers could be obtained by this kind of strategies.This review summarized and reviewed the recent advances in this field and classified these work according to the species of metal catalysts.

关 键 词：Asymmetric synthesis Transition metal catalysis Boronation reaction Cyclization reaction ENANTIOSELECTIVITY 

分 类 号：O62[理学—有机化学]