食品接触用一次性丁腈手套总迁移量的测定  

Determination on Overall Migration Quantity of Disposable Nitrile Gloves

作　　者：韦存茜 孙梦捷 夏铭德 WEI Cun-qian;SUN Meng-jie;XIA Ming-de(Shanghai Institute of Quality Inspection and Technical Research,Shanghai 201114,China)

机构地区：[1]上海市质量监督检验技术研究院,上海201114

出　　处：《合成材料老化与应用》2021年第2期37-39,共3页Synthetic Materials Aging and Application

基　　金：上海市科学技术委员会研发公共服务平台建设项目《上海市日用消费品质量安全检测专业技术服务平台》(项目编号:14DZ2293000)资助。

摘　　要：从电商平台上选购7批次食品接触用一次性丁腈手套作为样品,按照GB 4806.11-2016和GB 31604.8-2016所述方法,分别以4%乙酸、20%乙醇、50%乙醇为模拟物,测定丁腈手套在不同迁移时间和迁移方式下的总迁移量。结果表明,在40℃、2h的条件下仅有2批次合格,合格率为28.6%,总迁移量随时间延长而增大,迁移测试池法的试验结果小于全浸没法。为探究不合格原因,采用红外光谱(IR)和热失重分析(TGA)对样品进行进一步分析,结果发现不合格样品中填料较多。Seven batches of disposable nitrile gloves for food contact using were purchased from the e-commerce platform.These samples were determined by the methods given in the standards of GB 4806.11-2016 and GB 31604.8-2016.4%acetic acid,20%ethanol and 50%ethanol were taken as food simulants.Only 2 batches were qualified under the condition of 40℃and 2 h,and the pass rate was only 28.6%.The overall migration quantity was increased with the time extension.The result of migration pooltest was less than that of full immersion method.In order to investigate the cause of non-conformity,infrared spectroscopy(IR)and thermogravimetric analysis(TGA)were used for further analyzing.It was found that there are more fillers in the unqualified samples.

关 键 词：食品接触 丁腈手套 总迁移量 红外光谱 热失重分析 

分 类 号：O65[理学—分析化学]