A Mechanical Single-molecule Potentiometer Based on Foldamer  

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作  者:ZHAO Zhikai WANG Qingling XIANG Dong 

机构地区:[1]Tianjin Key Laboratory of Micro-scale Optical Information Science and Technology,Institute of Modern Optics,Nankai University,Tianjin,300350,P.R.China

出  处:《Chemical Research in Chinese Universities》2021年第2期335-336,共2页高等学校化学研究(英文版)

基  金:This work was supported by the National Natural Science Foundation of China(Nos.91950116,11804170);the Natural Science Foundation of Tianjin,China(Nos.19JCZDJC31000,19JCJQJC60900).

摘  要:Molecular potentiometers that can indicate displacement-conductance relationship and predict the molecular conductance are of significant importance towards the real application of molecule-based devices but rarely developed so far.To this end,Li et al.design a single-molecule potentiometer based on ortho-pentaphenylene derivatives.They demonstrated that these pseudoelastic molecules can be stretched and compressed by the mechanical force of the Au electrode along with a dramatically variable conductance by up to two orders of magnitude,demonstrating the great potential as angstrom-scale single-molecule potentiometers.This work has been published in Nature Communications,2021.

关 键 词:ELECTRODE DISPLACEMENT POTENTIAL 

分 类 号:O646[理学—物理化学]

 

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