PbO-FeO-CaO-SiO_(2)-ZnO五元渣系的熔化温度和黏度研究  

Study on Melting Temperature and Viscosity of PbO-FeO-CaO-SiO_(2)-ZnO System

作　　者：黄昊 张家靓 陈永强[1,2] 王成彦 HUANG Hao;ZHANGJia-liang;CHEN Yong-qiang;WANGCheng-yan(State Key Laboratoryof Advanced Metallurgy,University of Science and Technology Beijing,Beijing100083,China;School of Metallurgical and Ecological Engineering,University of Science and Technology Beijing,Beijing100083,China;Faculty of Materials Metallurgy and Chemistry,JiangxiUniversity of Science and Technology,Ganzhou 341000,Jiangxi,China)

机构地区：[1]北京科技大学钢铁冶金新技术国家重点实验室,北京100083 [2]北京科技大学冶金与生态工程学院,北京100083 [3]江西理工大学材料冶金化学学部,江西赣州341000

出　　处：《有色金属（冶炼部分）》2021年第5期11-16,共6页Nonferrous Metals（Extractive Metallurgy)

基　　金：广西创新驱动发展专项资金项目(AA18242042-1)。

摘　　要：在铅的富氧熔池熔炼中,高铅渣适宜的熔化温度和黏度对熔炼过程的顺行与高产有着至关重要的作用。以PbO-FeO-CaO-SiO2-ZnO五元渣系为研究对象,采用灰熔点测定仪测定炉渣熔化温度,采用内圆柱体旋转式快速高温黏度仪测定炉渣黏度,分别探讨了Fe/SiO2(质量比)(0.9~1.3)、CaO/SiO2(质量比)(0.4~0.8)及ZnO含量(5%~11%)对炉渣熔化温度和黏度的影响规律。结果表明,随着Fe/SiO2增加,炉渣的熔化温度和黏度都呈降低趋势,适宜的Fe/SiO2值为1~1.1;炉渣的熔化温度随CaO的增加有所提高,而黏度随着CaO含量的增加而降低,适宜的CaO/SiO2值为0.6;炉渣的熔化温度和黏度都随ZnO的增加而升高,在富氧熔池熔炼的操作温度内应保持ZnO含量低于7%。Melting temperature and viscosity of slag with high lead content play important role for up-flow and high yield in oxygen-enriched melting bath of lead.Taking PbO-FeO-CaO-SiO2-ZnO system as research object,melting temperature and viscosity of slag were measured by ash melting point measuring instrument and inner cylinder rotary high temperature viscosimeter respectively.Influence of Fe/SiO2 mass ratio(0.9-1.3),CaO/SiO2 mass ratio(0.4-0.8)and ZnO content(5%-11%)on melting temperature and viscosity of slag was investigated.The results show that melting temperature and viscosity of slag drop with increase of Fe/SiO2 ratio,and the appropriate Fe/SiO2 ratio is 1-1.1.Melting temperature of slag rises with increase of CaO content,while viscosity drops with increase of CaO content,and the appropriate CaO/SiO2 ratio is 0.6.Melting temperature and viscosity of slag rise with increase of ZnO content,and ZnO content should be kept to be below 7%in the operating temperature of oxygen-enriched melting process.

关 键 词：铅富氧熔池熔炼 高铅渣 熔化温度 黏度 

分 类 号：TF812[冶金工程—有色金属冶金]