含氟植物油多元醇的制备及其对PU膜性能的影响  

Preparation of Fluoride Vegetable-oil Polyol and the Effects on the Properties of Polyurethane Film

作　　者：王涵颖 蒋平平 翟英坤 赵敏仲 邓健能 曹志亮 WANG Hanying;JIANG Pingping;ZHAI Yingkun;ZHAO Minzhong;DENG Jianneng;CAO Zhiliang(School of Chemistry and Materials Engineering,Jiangnan University,Wuxi 214122,Jiangsu,China;Hebei Jingu Renewable Resources Development Co.Ltd,Shijiazhuang 052371,Hebei,China;Nantong Hairma Technology Co.Ltd,Nantong 226010,Jiangsu,China)

机构地区：[1]江南大学化学与材料工程学院,江苏无锡214122 [2]河北金谷再生资源开发有限公司,河北石家庄052371 [3]南通海珥玛植物油脂有限公司,江苏南通226010

出　　处：《聚氨酯工业》2021年第4期12-15,共4页Polyurethane Industry

基　　金：中央高校基本科研业务费专项资金资助(JUSRP51623A)。

摘　　要：以大豆油为原料,通过环氧化双键及三元开环反应合成了含氟大豆油基多元醇(SFP)。利用红外光谱和核磁氢谱等手段对该多元醇的结构进行表征,将合成的SFP和聚四氢呋喃二醇按不同比例混合并与异佛尔酮二异氰酸酯反应制得聚氨酯薄膜。结果表明,随着SFP用量的增加,聚氨酯膜对水静态接触角由74.8°提高到105.8°,以SFP制得的聚氨酯薄膜具有优越的疏水性能。Fluorine-containing soybean-oil based polyol(SFP)was synthesized from soybean oil by epoxidation and ring-opening reactions.The structure of the polyol was characterized by FT-IR and 1H-NMR,etc.Then,the polyurethane films were prepared by mixing SFP and poly-(tetra methylene glycol)in different proportions and reacting with isophorone diisocyanate.The results showed that the static contact angle of polyurethane films to water increased from 74.8°to 105.8°with the increase the SFP content,and the PU films prepared from SFP had excellent hydrophobic property.

关 键 词：大豆油 植物油基多元醇 疏水性 聚氨酯 

分 类 号：TQ323.8[化学工程—合成树脂塑料工业]