钠盐激发钢渣水泥的早期水化特性及动力学  

Early Hydration Properties and Kinetics of Steel Slag-Cement Activated by Sodium Salts

作　　者：张长森[1] 李杨[1,2] 胡志超 吴其胜 杨宇[1] ZHANG Changsen;LI Yang;HU Zhichao;WU Qisheng;YANG Yu(School of Materials Sciense and Engineering,Yancheng Institute of Technology,Yancheng 224051,China;School of Materials Science and Engineering,Changzhou University,Changzhou 213164,China;School of Materials Science and Engineering,Jiangsu University,Zhenjiang 212013,China)

机构地区：[1]盐城工学院材料科学与工程学院,江苏盐城224051 [2]常州大学材料科学与工程学院,江苏常州213164 [3]江苏大学材料科学与工程学院,江苏镇江212013

出　　处：《建筑材料学报》2021年第4期710-715,共6页Journal of Building Materials

基　　金：国家自然科学基金资助项目(51672236,51572234);江苏省生态建材与环保装备协同创新中心和江苏省新型环保重点实验室联合资助项目(CP201506)。

摘　　要：采用钠盐作为激发剂,通过水化热测定、扫描电镜(SEM)分析和水化动力学模拟,研究了不同钠盐激发钢渣水泥的早期水化进程、水化特性及其水化动力学.结果表明:钠盐掺入不影响钢渣水泥的水化进程,掺与不掺钠盐的钢渣水泥水化进程均分为起始快速放热期、诱导期、加速期、减速期和衰减期5个阶段;加速期水化反应由成核反应控制,属自催化反应;减速期水化反应由相边界反应与扩散机制共同控制;衰减期水化反应由扩散机制控制;由于反应机理的不同,加速期反应速率常数是衰减期的6~8倍,掺入钠盐的钢渣水泥反应速率常数大于未掺钠盐的,钠盐的掺入有助于钢渣水泥水化反应的进行,不同钠盐对水化的促进作用表现不同,加速期前铝酸钠对水化的促进效果较好,而到减速期后硅酸钠表现更佳.The early hydration process,hydration properties,and kinetics of steel slag cement activited by different sodium salts were studied through hydration heat measurement,scanning electron microscope(SEM)analysis,and hydration kinetics simulation.The results show that the incorporation of sodium salt does not affect the hydration process,and the hydration exothermic process of steel slag-cement with or without sodium salt can be divided into five stages:initial rapid exothermic stage,induction stage,acceleration stage,deceleration and attenuation stage.The acceleration stage hydration reaction is controlled by nucleation reaction,which belongs to the autocatalytic reaction.During the deceleration stage,the hydration reaction is jointly controlled by the phase boundary reaction and diffusion mechanism.In the attenuation stage,the hydration reaction is also controlled by diffusion mechanism.The reaction rate constant in the acceleration stage is 6 to 8 times of that in the attenuation stage due to the different reaction mechanisms.However,the reaction rate constant of steel slag-cement doped with sodium salt is greater than that without sodium salt.The addition of sodium salt is conductive to the hydration reaction of steel slag-cement.The promotion effect of different sodium salt on hydration is different.The promotion effect of sodium aluminate on hydration is better before the acceleration stage,and the promotion effect of sodium silicate is better after the deceleration stage.Different sodium salts have different promotion effects on hydration.The sodium aluminate promotes hydration better before the acceleration stage,while sodium silicate performs better after the deceleration stage.

关 键 词：钠盐 钢渣水泥 水化特性 水化动力学 

分 类 号：TQ172.4[化学工程—水泥工业]