三维正交群O_(3)-全部正八面体群O_(h)的V系数  

The V Coupling Coeffcients from O3 to Oh

作　　者：李前树 Li Qianshu(Institute of Theoretical Chemistry,Jilin University,Changchun)

机构地区：[1]吉林大学理论化学研究所

出　　处：《高等学校化学学报》1984年第4期535-540,共6页Chemical Journal of Chinese Universities

摘　　要：本文讨论了在具有连续群-点群意义的配位场理论方法中,采用O_(3)■0_(h)■D_(4h)(D_(3h))群链计算时的各类耦合系数,并表述成Ⅴ系数的形式,建立了它们与R_(3)■O■D_(4)(D_(3))群链的相应系数之间的关系。For the needs of treatment of ligand field theory with molecular orbital as the starting point,the relation between the three dimensional orthogonal group O_(3)and the full octahedral group O_(h)is discussed in detail,then the corresponding V-coupling coefficients from O_(3)to O_(h)is defined as an extension of those coefficents from R_(3)to octahedral group 0 which have been proposed by Tang et al.Under some symmetry rules,the numerical values of the coefficients from O_(3)to O_(h)can be directly obtained from the values of the coefficients from R_(3)to O without calculations.

关 键 词：配位场理论 (3) 耦合系数 

分 类 号：G63[文化科学—教育学]