两亲嵌段共聚物基高内相乳液模板的制备与应用研究进展  

Progress in preparation and application of amphiphilic block copolymer stabilized high internal phase emulsion templates

作　　者：李锦锦[1] 吴优 周寅宁[1] 罗正鸿[1] LI Jinjin;WU You;ZHOU Yinning;LUO Zhenghong(School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai 200420,China;College of Environmental and Chemical Engineering,Shanghai University of Electric Power,Shanghai 200090,China)

机构地区：[1]上海交通大学化学化工学院,上海200240 [2]上海电力大学环境与化学工程学院,上海200090

出　　处：《化工学报》2021年第11期5443-5454,共12页CIESC Journal

基　　金：国家自然科学基金青年项目(21808140)。

摘　　要：多孔聚合物材料具有孔隙率高、加工性能好、质量轻的特点,在化学工程、生物医学工程及环境工程等领域具有广阔的应用前景。高内相乳液模板法为多孔聚合物材料提供了一种简单高效的制备途径,且以此方法制备的多孔材料形状及结构可控,因而引起了人们的广泛关注。本文聚焦于两亲嵌段共聚物稳定的高内相乳液及其所制备多孔聚合物的最新研究进展。同时,介绍了该类型多孔聚合物材料在吸附分离、生物医学、能量存储及催化材料等领域的应用。最后,对该领域的未来发展进行了展望。Porous polymeric materials that possess high porosity,good processability,and light mass are widely used in chemical engineering,biomedical engineering,and environmental engineering.High internal phase emulsion(HIPE)templating provides a simple and efficient way to prepare porous polymer materials(i.e.,polyHIPEs),and the shape and structure of the as-prepared polyHIPEs can be well controlled,therefore,it receives a great deal of attentions.This article focuses on the recent research progress of amphiphilic block copolymer stabilized HIPEs and the preparation of porous polymers by HIPE templating.In addition,frontiers in the applications of such porous polymeric materials in the fields of adsorption and separation,biomedicine,energy storage,and catalytic materials are also introduced.Finally,the future development in both of the preparation and application of polyHIPEs are prospected.

关 键 词：高内相乳液 聚合 两亲嵌段共聚物 多孔聚合物材料 产品工程 

分 类 号：TQ317[化学工程—高聚物工业]