Bimetallic anchoring catalysis for C–H and C–C activation  

作　　者：Jiang-Fei Li Yu-Xin Luan Mengchun Ye 

机构地区：[1]State Key Laboratory and Institute of Elemento-Organic Chemistry,College of Chemistry,Frontiers Science Center for New Organic Matter,Nankai University,Tianjin,300071,China

出　　处：《Science China Chemistry》2021年第11期1923-1937,共15页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(91856104,21871145);the Tianjin Applied Basic Research Project and Cutting-Edge Technology Research Plan(19JCZDJC37900);“Frontiers Science Center for New Organic Matter”,Nankai University(63181206)。

摘　　要：Following the age of directing group,anchoring catalysis starts coming to the center of the stage.Different from the directinggroup strategy that needs a preinstalled directing group in substrates,anchoring catalysis relies on a reversible interaction between a substrate and a catalyst,which then directs metal to activate inert chemical bonds.Such reversible directing effect not only generates good site-and stereo-selectivity as traditional directing groups do but also eliminates the requirement of stoichiometric amounts of directing groups.Among variously reported anchoring catalysis,coordinative bimetallic anchoring catalysis in general displays superior reactivity than others because coordinative bonding not only affords strong interaction of catalysts with substrates but also displays good compatibility with substrates and reaction conditions.In recent years,big progress has been achieved for coordinative bimetallic anchoring catalysis.This review gave a detailed summary of this field,including catalyst development,catalyst types,reaction types and reaction mechanisms.

关 键 词：C–H activation C–C activation bimetallic catalysis ENANTIOSELECTIVE anchoring catalysis 

分 类 号：O621.251[理学—有机化学]