光学活性和手性光谱的溯源和发展  

Traceability and Development of Optical Activity and Chiroptical Spectroscopy

作　　者：章慧[1] 齐爱华 李丹 李荣兴 Hui Zhang;Aihua Qi;Dan Li;Rongxing Li(College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,Fujian Province,China;Dalian Huayang Analytical Instruments Co.,Ltd.,Dalian 116001,Liaoning Province,China)

机构地区：[1]厦门大学化学化工学院,福建厦门361005 [2]大连华洋分析仪器有限公司,辽宁大连116001

出　　处：《大学化学》2022年第1期214-229,共16页University Chemistry

摘　　要：概述了19世纪以来光学活性和手性光谱的发现和发展,着重对旋光色散(ORD)、电子圆二色(ECD)和振动圆二色(VCD)光谱的发展背景和基本原理作出介绍。其中特别提及华人科学家徐光宪和徐云洁在手性光谱发展历程中的杰出贡献。This paper presents a comprehensive overview on the discovery and development of optical activity and chiroptical spectroscopy since the nineteenth century, with emphasis on the background and basic principles of the development of optical rotatory dispersion(ORD), electron circular dichroism(ECD) and vibrational circular dichroism(VCD) spectroscopy. Therein, the outstanding contributions of Chinese scientists Guangxian Xu and Yunjie Xu in the development of chiroptical spectroscopy are specifically mentioned.

关 键 词：光学活性和手性光谱史 旋光色散(ORD) 电子圆二色(ECD) 振动圆二色(VCD) 

分 类 号：G64[文化科学—高等教育学] O6[文化科学—教育学]