醇类香料单体应用于滤棒加香的转移行为研究  

Study on the transfer behavior of alcohol flavors used in filter stick perfuming

作　　者：杨龙彦[1] 张玎婕 宁振兴[1] 李志华[1] 李季刚[1] 黄善松[1] 张峻松 YANG Longyan;ZHANG Dingjie;NING Zhenxing;LI Zhihua;LI Jigang;HUANG Shansong;ZHANG Junsong(Technology Center,China Tobacco Guangxi Industrial Co.,Ltd.,Nanning 530001,China;College of Food and Bioengineering,Zhengzhou University of Light Industry,Zhengzhou 450001,China)

机构地区：[1]广西中烟工业有限责任公司技术中心,广西南宁530001 [2]郑州轻工业大学食品与生物工程学院,河南郑州450001

出　　处：《轻工学报》2022年第1期87-94,共8页Journal of Light Industry

基　　金：河南省科技攻关项目(182102310647);广西中烟工业有限责任公司科技项目(2020450000340026)。

摘　　要：将13种醇类香料单体添加到卷烟滤棒中,优化香料成分的萃取条件,建立香料单体的GC-MS分析方法,考查贮存和抽吸过程中醇类香料单体在卷烟中的转移行为。结果表明:1)当萃取溶剂为无水乙醇、萃取方式为超声振荡、萃取溶剂体积为6 mL、萃取时间为20 min时,醇类香料单体萃取量最高。2)13种醇类香料单体在0.63~10.00μg/mL质量浓度范围内线性良好,精密度、回收率较高,该分析方法可行。3)贮存期13种醇类香料的滤嘴持留率为9.68%~52.03%,烟丝迁移率为1.06%~17.36%,散失率为36.88%~87.01%;抽吸后13种醇类香料单体主流烟气转移率为0~14.49%,滤嘴残留率为14.78%~73.25%。4)十五醇的滤嘴持留率、烟气转移率相对较高,烟丝迁移率、散失率、滤嘴残留率相对较低,适宜应用于滤棒加香。5)互为顺反异构体的醇类香料单体在卷烟贮存和抽吸过程中的转移行为较相似;互为同系物的醇类香料单体,滤嘴持留率、烟气转移率、滤嘴残留率整体上随分子量增大、沸点增高而逐渐增加,散失率则逐渐减小。13 kinds of alcohol flavors were added to cigarette filter rods, the extraction conditions of flavors in cigarettes were optimized, the GC-MS analysis method of alcohol homologous compounds was established, and the transfer behavior of alcohol flavors in cigarettes during storage and smoking was studied. The results showed that: when the extraction solvent was absolute ethanol, the extraction method was ultrasonic vibration, the extraction solvent volume was 6 mL, the extraction time was 20 minutes, the extraction amount of alcohol flavors was the highest. The linearity of 13 alcohol flavors was good in the concentration range of 0.63~10.00 μg/mL, and the precision and recovery rate were high. During storage period, the filter retention rate of 13 alcohol flavors was 9.68%~52.03%, the migration rate of tobacco was 1.06%~17.36%, and the loss rate was 36.88%~87.01%;during smoking, the mainstream smoke transfer rate of 13 alcohol flavors was 0~14.49%, the filter residue rate was 14.78%~73.25%. The filter retention rate and the smoke transfer rate of pentadecanol were relatively high high, the tobacco migration rate, the loss rate, and the filter residue rate were relatively low, so it was suitable for being used in the filter-flavored cigarettes. The transfer behavior of alcohol flavors that were cis and trans isomers were similar during storagin and smoking;alcohol flavors that were homologous to each other had similar transfer behaviors. In summary, with the molecular weight and boiling point increasing, the filter retention rate, flue gas transfer rate, and filter residue rate gradually increased, while the loss rate gradually decreased.

关 键 词：醇类香料 滤棒加香 滤嘴持留率 烟丝迁移率 烟气转移率 滤嘴残留率 

分 类 号：TS246.3[轻工技术与工程—制糖工程]