Effect and Influence of Aryl Mercaptanes with Various Chain Lengths on DNA/RNA and Cadmium Oxide (CdO) Nanoparticles Sandwiched Complex  

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作  者:Alireza Heidari 

机构地区:[1]Faculty of Chemistry,California South University,14731 Comet St.Irvine,CA 92604,USA [2]BioSpectroscopy Core Research Laboratory,California South University,14731 Comet St.Irvine,CA 92604,USA [3]Cancer Research Institute(CRI),California South University,14731 Comet St.Irvine,CA 92604,USA [4]American International Standards Institute,Irvine,CA 3800,USA

出  处:《材料科学与工程(中英文A版)》2021年第4期129-142,共14页Journal of Materials Science and Engineering A

摘  要:CdO(cadmium oxide)nanoparticles show a strong peak of Plasmon absorption in ultraviolet-visible zone.A strong interaction exists between the surface of CdO nanoparticles and aryl mercaptan compounds.Aryl mercaptan compounds cause aggregation of CdO nanoparticles linked to DNA/RNA(eoxyribonucleic acid/ribonucleic acid)and hence,lead to widening of peak Plasmon of CdO nanoparticles surface at 550 nm and emerge a new peak at higher wavelength.In the current project,this optical characteristic of CdO nanoparticles is used to investigate interaction time between different aryl mercaptanes and CdO nanoparticles.The results showed that aryl mercaptan compounds with shorter chain length interact faster with CdO nanoparticles.Therefore,a simple and fast method for identification of aryl mercaptanes with various chain lengths using red shift in surficial Plasmon absorption is presented.

关 键 词:Aryl mercaptans peak Plasmon absorption AGGREGATION CdO nanoparticles DNA/RNA. 

分 类 号:O62[理学—有机化学]

 

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