钒基负极材料在锂离子电容器中的应用  

Application of Vanadium-Based Anode Materials for Lithium-Ion Capacitors

作　　者：陈子洋 任正鸿 张金慧 申来法[1] CHEN Ziyang;REN Zhenghong;ZHANG Jinhui;SHEN Laifa(Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies,College of Material Science and Technology,Nanjing University of Aeronautics and Astronautics,Nanjing 211106,Jiangsu,China)

机构地区：[1]南京航空航天大学材料科学与技术学院,江苏省高效电化学储能技术重点实验室,南京211106

出　　处：《硅酸盐学报》2022年第1期101-109,共9页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金(U1802256,52072173);江苏省特聘教授计划;江苏省杰出青年基金(BK20200016)。

摘　　要：锂离子电容器一个电极采用电池型负极,一个采用电容型正极,因而兼具高能量密度、高功率密度的优点,有望成下一代新型储能器件。基于Faraday反应的电池型电极与电容型电极动力学不匹配是锂离子电容器的一个巨大挑战,因此研究者们发展了多种倍率性锂离子电池材料。在这些材料中,钒基材料以其成本低、比容量大、倍率性能优异等优点被认为是锂离子电容器的理想负极材料。综述了包括Li_(3)VO_(4)、VN、Li_(3)V_(2)O_(5)在内的多种不同类型钒基锂离子电池材料的储锂机理与性能优化的研究进展,并展望了锂离子电容器中钒基负极材料的发展方向。Lithium-ion capacitor has structure of consisting of the battery-type anode and capacitor-type cathode,thus having a enabling high energy density and a high power density.This capacitor expected to become the next generation of new energy storage devices.The kinetic mismatch between the Faradaic battery-type anode and capacitive cathode is a great challenge for lithium-ion capacitors.Therefore,researchers have developed a variety of high-rate lithium-ion battery materials.Among these materials,vanadium-based materials are considered as ideal anode materials for lithium-ion capacitor due to their low cost,large specific capacity,and superior rate performance.This review summarized recent work on the optimization strategies of several vanadium-based anode materials,i.e.Li_(3)VO_(4),VN and Li_(3)V_(2)O_(5).In addition,the future directions in the application of vanadium-based anode materials for lithium-ion capacitor were also proposed.

关 键 词：锂离子电容器 负极 钒酸锂 氮化钒 锂钒氧化物 

分 类 号：TM53[电气工程—电器]