Visible-light-mediated tungsten-catalyzed C-H amination of unactivated alkanes with nitroarenes  

作　　者：Qing Wang Shengyang Ni Xiaochen Wang Yi Wang Yi Pan 

机构地区：[1]State Key Laboratory of Coordination Chemistry,Jiangsu Key Laboratory of Advanced Organic Materials,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China

出　　处：《Science China Chemistry》2022年第4期678-685,共8页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(21772085,21971107,2201101);China Postdoctoral Science Foundation(2021T140309,2021M691511)。

摘　　要：Alkylamines are important motifs in pharmaceutical and material sciences.The existing reports of C-H amination are limited to ammonia,diazo and azide nitrogen sources.This work describes a rapid construction of C-N bonds from accessible nitroarene and alkane feedstock under decatungstate catalysis.A variety of C-H precursors including gaseous,linear,cyclic and benzylic hydrocarbons could adopt this protocol to afford the corresponding alkylamines in high efficiency.

关 键 词：AMINATION PHOTOREDOX light alkane NITROBENZENE 

分 类 号：O622.6[理学—有机化学]