3,4-二氨基呋咱合成及其含能衍生物研究进展  

Research Progress on the Synthesis of 3,4-Diaminofurazan and Its Energetic Derivatives

作　　者：折巍青 翟连杰[1,3] 李建康 黄洁[2] 王伯周[1,3] SHE Wei-qing;ZHAI Lian-jie;LI Jian-kang;HUANG Jie;WANG Bo-zhou(Xi′an Modern Chemistry Research Institute,Xi′an 710065,China;School of Chemical Engineering,Northwest University,Xi′an 710069,China;State Key Laboratory for Efficient Development and Utilization of Fluorine and Nitrogen Chemical Resources,Xi′an 710065,China)

机构地区：[1]西安近代化学研究所,陕西西安710065 [2]西北大学化工学院,陕西西安710069 [3]氟氮化工资源高效开发与利用国家重点实验室,陕西西安710065

出　　处：《火炸药学报》2022年第2期179-192,I0002,共15页Chinese Journal of Explosives & Propellants

基　　金：国家自然科学基金(No.21805224)。

摘　　要：介绍了高压法、微波法、常压法3种3,4-二氨基呋咱(DAF)的合成方法,并对其优缺点进行了评述。基于DAF氨基可发生硝化、氧化、重氮化等反应特性,系统阐述了单呋咱、二呋咱偶氮、多呋咱以及稠环呋咱等DAF含能衍生物的合成方法,同时重点介绍了相关含能化合物的物化与爆轰性能。指出由于DAF制造成本偏高、规模小,严重制约着DAF含能衍生物在武器装备中的应用,需要开展DAF低成本制造工艺研究;应进一步拓展DAF含能衍生物合成研究,有望构建、合成性能优异的新一代含能材料,以满足含能材料领域的实际应用需求。Three synthetic strategies of 3,4-diaminofurazan(DAF)including high pressure method,microwave method and atmospheric pressure method were fully introduced,and their advantages and disadvantages were briefly reviewed.Based on the reaction characteristics of DAF amino group,such as nitration,oxidation and diazotization,the synthetic methods of furazan energetic derivatives including monofurazan,bisfurazan,polyfurazan and fused furazan were systematically described,and their physicochemical properties and detonation performances were also introduced.Due to the high manufacturing cost and small scale of DAF,the application of DAF energetic derivatives in weapons and equipment is seriously restricted,and it is necessary to study the low-cost manufacturing process of DAF.The research on the synthesis of DAF energetic derivatives was further expanded,and it was expected to construct and synthesize a new generation of energetic materials with excellent properties,in order to meet the practical application needs in the field of energetic materials.

关 键 词：有机化学 3 4-二氨基呋咱 DAF 呋咱含能化合物 爆轰性能 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O62[理学—有机化学]