Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters  

作　　者：Jian-Jun Dai Xin-Xin Teng Wen Fang Jun Xu Hua-Jian Xu 

机构地区：[1]School of Food and Biological Engineering,Hefei University of Technology,Hefei 230009,China [2]Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering,Hefei University of Technology,Hefei 230009,China

出　　处：《Chinese Chemical Letters》2022年第3期1555-1558,共4页中国化学快报（英文版）

基　　金：supported by the National Natural Science Foundation of China (Nos. 21871074 and 21971051);the National Key R&D Program of China (No. 2018YFB1501604);the Fundamental Research Funds for the Central Universities (No. PA2020GDKC0021);the Key Research and Development Program Projects in Anhui Province (No. 201904a07020069)。

摘　　要：An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal-or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical conditions. This reaction exhibits broad substrate scope, good functional group tolerability, and easy scalability.

关 键 词：ELECTROCHEMICAL DECARBOXYLATION BORYLATION Alkyl boronic esters Redox active esters 

分 类 号：O621.25[理学—有机化学]