云南高校图书馆联盟文献共享服务平台- BORYLATION

BORYLATION: 作品数：36被引量：25H指数：2; 导出分析报告; 相关领域：理学更多>>; 相关机构：国立台北科技大学更多>>; 相关期刊：《Green Synthesis and Catalysis》《Precision Chemistry》《National Science Review》《Chinese Journal of Catalysis》更多>>; 相关基金：国家自然科学基金中国博士后科学基金国家重点基础研究发展计划天津市自然科学基金更多>>

Enantio-divergent C–H borylation with two different ligands from a single chiral source: 《Science China Chemistry》2025年第1期226-232,共7页Rongrong Du Senmiao Xu; supported by the National Key R&D Program of China(2022YFA1504302);the National Natural Science Foundation of China(92256302,22331011);the Natural Science Foundation of Jiangsu Province(BK20211092);the Major Program of the Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences(ZYFZFX-9);the Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences;the Hangzhou Normal University。; Reported here is an iridium-catalyzed enantio-divergent C(sp^(3))–H borylation ofα-gem-dimethyl groups of trifluoromethyl ketone-derived hydrazones to construct a series of acyclic all-carbon quaternary stereocenter...; 关键词：asymmetric catalysis C–H borylation all-carbon quaternary stereocenters synthetic methods

Recent Advances in Methodologies for Radical-Mechanistic Borylation: 《Chinese Journal of Chemistry》2025年第1期104-115,共12页Chang Lian Jianning Zhang Di Qiu Fanyang Mo; National Natural Science Foundation of China(Grant Nos.22071004,21933001 and 22150013)for financial support.; We reviewed works on radical borylation reactions since 2020 from two aspects.1.Borylation from alkyl or aryl radicals:This approach involves the generation of alkyl or aryl radicals from various precursors such as ha...; 关键词：Radical reactions Radicalmechanisms Organic methodologies Green chemistry BORANES

Decarboxylative and Decarbonylative Borylation of Carboxylic Acids and Their Derivatives: 《Chinese Journal of Chemistry》2024年第24期3429-3440,共12页Xiaoxian Li Lipeng Wu; the National Natural Science Foundation of China(22271295);Gansu Provincial Natural Science Foundation Key Project(23JRRA606);Major Program of the Lanzhou Institute of Chemical Physics,CAS(No.ZYFZFX-9);State Key Laboratory Program of the Lanzhou Institute of Chemical Physics(CHGZ-202208)for generous financial support.; Boronate esters are highly valued in synthetic and pharmaceutical industries for their versatility in creating C—C and C—X bonds.They also find applications as catalysts in chemical transformations as well as stimul...; 关键词：DECARBOXYLATION BORYLATION DECARBONYLATION Carboxylic acid DERIVATIVES AMIDES Transition metals Catalysis

Photoelectrochemical Iron-Catalyzed C(sp^(3))-H Borylation of Alkanes in a Position-Selective Manner: 《CCS Chemistry》2024年第6期1430-1438,共9页Wen Wei Bin Wang Simon L.Homölle Jinbin Zhu Yanjun Li Tristan von Münchow Isaac Maksso Lutz Ackermann; the European Research Council(ERC Advanced Grant;no.101021358);the Deutsche Forschungsgemeinschaft(DFG,Gottfried Wilhelm Leibniz award to L.A.);the Fonds der Chemischen Industrie(FCI,Kekulé-Fellowship to T.v.M.);the China Scholarship Council(CSC grant no.201906280067 to W.W.).; Catalytic C-H borylation is of prime topical importance,since easily available feedstock chemicals can thereby be transformed into valuable transient functional groups in the absence of directing groups.Herein,we disc...; 关键词：PHOTOELECTROCATALYSIS C(sp^(3))-H borylation iron catalysis position-selectivity chlorine radical

Terminal-selective C(sp^(3))-H borylation of unbranched alkanes enabled by intermolecular radical sampling and LMCT photocatalysis: 《National Science Review》2024年第5期89-91,共3页Zhexuan Lei Jie Wu; The selective functionalization of C(sp^(3))–H bonds with subtle differences in alkanes is highly sought after due to its atom-and step-efficiency.The activation of C(sp^(3))–H bonds through hydrogen atom transfer(H...; 关键词：BONDS ALKANES STERIC

Cu-catalyzed regioselective diborylation of 1,3-enynes for the efficient synthesis of 1,4-diborylated allenes: 《Chinese Chemical Letters》2024年第5期141-144,共4页Wujun Jian Mong-Feng Chiou Yajun Li Hongli Bao Song Yang; supported by the National Natural Science Foundation of China(NSFC,Nos.22001251,21922112,and 22225107);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);National Key R&D Program of China(No.2017YFA0700103);the Guizhou Provincial S&T Project(No.2018[4007]).; Borylation of 1,3-enynes with bis(boronate)compounds often ends up with the formation of hydroborylated products,leaving the diborylation of 1,3-enynes for the formation of 1,4-diborylated allenes to be challenging.He...; 关键词：Copper catalysis REGIOSELECTIVE 1 3-Enynes BORYLATION ALLENES

Cobalt-catalyzed deoxygenative borylation of diaryl ketones被引量：1: 《Chinese Chemical Letters》2024年第3期277-281,共5页Longqing Liu Bing Zhang Yu Liu Jinbo Zhao Tao Li Wanxiang Zhao; financial support from the National Natural Science Foundation of China(Nos.22271086 and 21971059);the National Program for Thousand Young Talents of China;the Fundamental Research Funds for the Central Universities。; Geminal diboronates and diarylmethyl boronates are versatile building blocks in synthetic chemistry.We here reported a highly efficient approach for the synthesis of gem-bisborylalkanes and diarylmethyl boronates via ...; 关键词：Bisborylalkanes COBALT Deoxygenative borylation KETONES

Synthesis,Structures,and Chiroptical Properties of NBN-Doped Helicenes with Boron Atoms in the Inner Rims: 《Precision Chemistry》2024年第1期28-39,共12页Weiwen Zhuang Yujian Liu Ziqi Deng Yu Guo Philip C.Y.Chow David Lee Phillips Wei Jiang Zhaohui Wang Junzhi Liu; supported by the Hong Kong Research Grants Council(27301720,17304021);National Natural Science Foundation of China(22122114,22122503,21790361).; The precise synthesis of helicenes with topologically defined length and specific heteroatomic perturbation in the screw-like conjugated skeletons plays an emerging role in the manipulation of chiral materials.Facile,...; 关键词：Nitrogen-boron HELICENES BORYLATION Chiroptical properties Narrow-band emission

Synergistic Pd/Cu-catalyzed regio-and stereoselective cascade Heck cyclization/borylation/cross-coupling: 《Chinese Chemical Letters》2023年第12期166-171,共6页Yifan Wang Yuanyuan Ping Wangqing Kong; financial support from the National Natural Science Foundation of China(No.22171215);the Excellent Youth Foundation of Hubei Scientific Committee(No.2022CFA092);the GuangDong Basic and Applied Basic Research Foundation(No.2022A1515110113).; A cooperative Pd/Cu-catalyzed three-component cross-coupling reaction of alkynes,B_(2)Pin_(2) and alkene-tethered aryl halides is reported.This reaction proceeds under mild conditions and shows broad sub-strate scope,...; 关键词：Palladium/copper catalysis Heck cyclization Alkene difunctionalization CROSS-COUPLING BORYLATION

Protecting-group-free ortho-C–H borylation of anilines enabled by mesoionic carbene-Ir complex: 《Green Synthesis and Catalysis》2023年第4期300-305,共6页Zengyu Zhang Shiqing Huang Wei Liu Liang-Liang Zhao Chubin Hu Xiaoyu Yan; This work was supported by the National Natural Science Foundation of China(Nos.22171284 and 21602249);the Fundamental Research Funds for the Central Universities,the Research Funds of Renmin University of China(No.20XNLG20);the Public Computing Cloud Platform,Renmin University of China.; We describe an iridium-catalyzed ortho-selective C–H borylation of unprotected anilines.The employing strongσ-donating cyclometalated mesoionic carbene as C^C bidentate ligand is crucial for the high ortho-selectivi...; 关键词：Protecting-group-free C-H borylation Hydrogen bonding Regioselectivity Mesoionic carbene

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