financial support from the National Natural Science Foundation of China(No.22208279);Financial support from the Fuzhou University(No.0041/511095)。
A visible light-promoted fast photochemical Wolff rearrangement was developed toward synthesis ofα-substituted amides in continuous flow with the use of a photochemical oscillatory flow reactor(POFR).The control expe...
financial support from the National Natural Science Foundation of China(No.22171249);the Science&Technology Innovation Talents in Universities of Henan Province(No.23HASTIT003)。
The development of innovative and sustainable catalytic strategies for organic synthesis is a pivotal aspect of advancing material science and chemical engineering.This research presents a new catalytic method for the...
financial support from the National Natural Science Foundation of China(No.82003585);the Program for Science&Technology Innovation Talents in Universities of Henan Province(No.24HASTIT069);the Technical Innovation Team of Henan Normal University(No.2022TD03);the Special Project for Fundamental Research in University of Henan Province(No.23ZX009);the Henan Science and Technology Program(No.232102310364);the Key Project of Henan Educational Committee(No.22A150041);Excellent Youth Foundation of Henan Scientific Committee(No.222300420012);the Young Core Instructor Training Program of Xinyang Agriculture and Forestry University(2023)。
A transition-metal-and oxidant-free amination/cyclization reaction to access 1,2,4-triazolo[1,5-a]pyridines was realized in water by using amino diphenylphosphinate as amino source.A broad array of readily accessible ...
the National Natural Science Foundation of China(22271295);Gansu Provincial Natural Science Foundation Key Project(23JRRA606);Major Program of the Lanzhou Institute of Chemical Physics,CAS(No.ZYFZFX-9);State Key Laboratory Program of the Lanzhou Institute of Chemical Physics(CHGZ-202208)for generous financial support.
Boronate esters are highly valued in synthetic and pharmaceutical industries for their versatility in creating C—C and C—X bonds.They also find applications as catalysts in chemical transformations as well as stimul...
National Natural Science Foundation of China(Nos.42388101,92256203,and 42003062);Fundamental Research Funds for the Provincial Universities of Zhejiang(No.SJLY2023007);Technology and Engineering Center for Space Utilization,Chinese Academy of Sciences(No.YYWT-0901-EXP-16);Ningbo Top Talent Project(No.215-432094250).
The prebiotic synthesis of peptides prior to ribosome-catalyzed processes remains an enigma.The synthesis of abiotic peptides from amino acids(AAs)is primarily constrained by high activation energies and unfavorable t...
financial support from the National Natural Science Foundation of China(Grant Nos.22071188,22371217);Hubei Provincial Natural Science Foundation of China(2023AFA011).
The first asymmetric hydrogenation of acyclic tetrasubstitutedα,β-unsaturated amides has been achieved by using Rh/DuanPhos complex as a catalyst,delivering chiralβ-amino amides with two contiguous chiral centers i...
Based on a strategy of ground-state destabilisation of the N—C bond,a general protocol for the esterification of amides with carbohydrates was reported.This protocol offers mild reaction conditions,excellent yields,a...
The National Key Research and Development Program of Ministry of Science and Technology(No.2022YFA1504602);Natural Science Foundation of Jiangsu Province(No.BK20211094);National Natural Science Foundation of China(No.22302214,21972152,U22B20137).
Carbonylation reactions,crucial for carbonyl group incorporation,struggle with the inherent complexity of achieving selective mono-or double-carbonylation on single substrates,often due to competing reaction pathways....
supported by the National Natural Science Foundation of China(No.62005108,No.62205134);the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(No.21KJB140008);the Graduate Research and Practice Innovation Program of Jiangsu Normal University(No.2021XKT1201,No.2021XKT1204).
The interaction of proteins with salt ions plays an important role in life activities.We used butyramide as a model molecule to investigate the interaction of protein backbones with cations.The experiment was performe...
supported by the National Natural Science Foundation of China(Nos.21901185 and 22301216);funds provided by Tianjin Normal University。
Herein,we report the migratory hydroarylation of unactivated alkenes with aryl iodides using native and weakly coordinating amide directors under mild conditions.Synergistic coordination of the monodentate directing g...