Decarboxylative and Decarbonylative Borylation of Carboxylic Acids and Their Derivatives  

作　　者：Xiaoxian Li Lipeng Wu 

机构地区：[1]State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics(LICP),Chinese Academy of Sciences,Lanzhou,Gansu 730000,China [2]College of Material Chemistry and Chemical Engineering,Key Laboratory of Organosilicon Chemistry and Material Technology,Ministry of Education,Hangzhou Normal University,Hangzhou,Zhejiang 311121,China

出　　处：《Chinese Journal of Chemistry》2024年第24期3429-3440,共12页中国化学(英文版)

基　　金：the National Natural Science Foundation of China(22271295);Gansu Provincial Natural Science Foundation Key Project(23JRRA606);Major Program of the Lanzhou Institute of Chemical Physics,CAS(No.ZYFZFX-9);State Key Laboratory Program of the Lanzhou Institute of Chemical Physics(CHGZ-202208)for generous financial support.

摘　　要：Boronate esters are highly valued in synthetic and pharmaceutical industries for their versatility in creating C—C and C—X bonds.They also find applications as catalysts in chemical transformations as well as stimuli-responsive materials in materials science.Some alkyl boronates themselves also show promising applications in medicinal chemistry.In the past few decades,chemists have been devoted to developing new methods or new starting materials for synthesizing boronate esters.Carboxylic acids and their derivatives are privileged chemical entities due to their readily availability or natural abundance,structural diversity,and chemical stability.Hence,the transformation of carboxylic acid and their derivatives to alkyl/aryl boronate esters has seen its fast development in the past decade.This review summarized the state-to-art development of decarboxylative and decarbonylative borylation of carboxylic acids and their derivatives to aryl and alkyl boronate esters.

关 键 词：DECARBOXYLATION BORYLATION DECARBONYLATION Carboxylic acid DERIVATIVES AMIDES Transition metals Catalysis 

分 类 号：O62[理学—有机化学]