DECARBONYLATION

作品数:18被引量:13H指数:2
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相关领域:理学更多>>
相关作者:陈大发更多>>
相关机构:哈尔滨工业大学更多>>
相关期刊:《China Petroleum Processing & Petrochemical Technology》《Frontiers of Chemical Science and Engineering》《Journal of Wuhan University of Technology(Materials Science)》《Science China Chemistry》更多>>
相关基金:国家自然科学基金天津市自然科学基金国家重点基础研究发展计划国家高技术研究发展计划更多>>
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Decarboxylative and Decarbonylative Borylation of Carboxylic Acids and Their Derivatives
《Chinese Journal of Chemistry》2024年第24期3429-3440,共12页Xiaoxian Li Lipeng Wu 
the National Natural Science Foundation of China(22271295);Gansu Provincial Natural Science Foundation Key Project(23JRRA606);Major Program of the Lanzhou Institute of Chemical Physics,CAS(No.ZYFZFX-9);State Key Laboratory Program of the Lanzhou Institute of Chemical Physics(CHGZ-202208)for generous financial support.
Boronate esters are highly valued in synthetic and pharmaceutical industries for their versatility in creating C—C and C—X bonds.They also find applications as catalysts in chemical transformations as well as stimul...
关键词:DECARBOXYLATION BORYLATION DECARBONYLATION Carboxylic acid DERIVATIVES AMIDES Transition metals Catalysis 
Ligand enabled none-oxidative decarbonylation of aliphatic aldehydes
《Chinese Chemical Letters》2023年第7期107-111,共5页Bo Li Shihao Liu Wu Fan Xiaotong Shen Jing Xu Suhua Li 
financial support from the National Natural Science Foundation of China (No. 21971260);Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2018B030306018);the Program for Guangdong Introducing Innovative and Entrepreneurial Teams (No. 2017ZT07C069);the Pearl River Talent Recruitment Program (No. 2019QN01L111);the Fundamental Research Funds for the Central Universities, Sun Yatsen University (No. 22lglj06);Innovation projects of Zhengzhou tobacco research institute (No. 442020CR0320 to Wu Fan)。
Decarbonylation of aldehydes is a basic organic transformation, which has been developed for more than six-decade. However, as comparing to well-studied aromatic aldehydes, fewer examples for catalytic decarbonylation...
关键词:DECARBONYLATION Aliphatic aldehydes RHODIUM IRIDIUM LIGAND 
Catalytic Elimination of Oxygenated Byproducts in the Toluene Methylation Process
《China Petroleum Processing & Petrochemical Technology》2023年第2期65-73,共9页Hou Min Qi Xiaolan Zheng Junlin 
We gratefully acknowledge the support from the National 973 Program of China(Grant No.2003CB615800).
Catalytic methylation of toluene with methanol is an important alternative pathway for xylene production.Previous studies have indicated that methanol always undergoes several side reactions on acidic zeolites,resulti...
关键词:XYLENE catalytic methylation DECARBONYLATION TOLUENE MgO catalyst 
Efficient hydrothermal deoxygenation of methyl palmitate to diesel-like hydrocarbons on carbon encapsulated Ni–Sn intermetallic compounds with methanol as hydrogen donor被引量:1
《Frontiers of Chemical Science and Engineering》2023年第2期139-155,共17页Haonan Shi Xiaoyu Gu Yinteng Shi Dandan Wang Sihao Shu Zhongze Wang Jixiang Chen 
Porous carbon-encapsulated Ni and Ni-Sn intermetallic compound catalysts were prepared by the one-pot extended Stöber method followed by carbonization and tested for in-situ hydrothermal deoxygenation of methyl palmit...
关键词:extended Stöber method carbon encapsulated Ni-Sn intermetallic compounds confinement in-situ hydrothermal deoxygenation HYDROGENATION DECARBONYLATION 
Carbon-coated Ni-Co alloy catalysts:preparation and performance for in-situ aqueous phase hydrodeoxygenation of methyl palmitate to hydrocarbons using methanol as the hydrogen donor
《Frontiers of Chemical Science and Engineering》2022年第4期443-460,共18页Yinteng Shi Lin Ai Haonan Shi Xiaoyu Gu Yujun Han Jixiang Chen 
support from the National Natural Science Foundation of China(Grant Nos.21576193,21176177).
Carbon-coated Ni,Co and Ni-Co alloy catalysts were prepared by the carbonization of the metal doped resorcinol-formaldehyde resins synthesized by the one-pot extended Stöber method.It was found that the introduction o...
关键词:Stöber method carbon-coated Ni-Co alloy in-situ hydrodeoxygenation methyl palmitate DECARBONYLATION decarboxylation 
Palladium-catalyzed diarylative dearomatization of indoles with aryl thioesters被引量:1
《Chinese Chemical Letters》2021年第9期2765-2768,共4页Wei Huang Ming-Liang Han Yu-Wen Liu Hui Xu Hui-Xiong Dai 
the Shanghai Institute of Materia Medica;the Chinese Academy of Sciences;the National Natural Science Foundation of China(Nos.21772211 and 21920102003);the Youth Innovation Promotion Association CAS(Nos.2014229 and 2018293);the Science and Technology Commission of Shanghai Municipality(Nos.17JC1405000 and 18431907100);the Program of Shanghai Academic Research Leader(No.19XD1424600);the National Science&Technology Major Project“Key New Drug Creation and Manufacturing Program”,China(No.2018ZX09711002-006)for financial support。
We report herein a palladium-catalyzed diarylative dearomatization of indole by employing thioester and arylboronic acid as the aryl electrophiles.The reaction involved a decarbonylation/migratory insertion/terminal S...
关键词:THIOESTER DECARBONYLATION DEAROMATIZATION Indolines skeleton Diarylation 
Dimethyl sulfoxide-aided copper(0)-catalyzed intramolecular decarbonylative rearrangement of N-aryl isatins leading to acridones
《Chinese Chemical Letters》2020年第6期1580-1583,共4页Hao Wu Nana Ma Mengxiao Song Guisheng Zhang 
National Natural Science Foundation of China(Nos.U1604285 and 21877206);the Program for Changjiang Scholars and Innovative Research Team in University of China(No.IRT1061);the 111 Project(No.D17007)。
Described here is the first example of Cu(0)-catalyzed intramolecular decarbonylative rearrangements of readily available N-aryl isatins assisted by solvent dimethyl sulfoxide(DMSO)under air atmosphere and additive-fr...
关键词:Cu(0)-catalyzed decarbonylation Decarbonylative rearrangements DMSO-aided reactions N-Aryl isatins ACRIDONES 
Remarkably reducing carbon loss and H2 consumption on Ni–Ga intermetallic compounds in deoxygenation of methyl esters to hydrocarbons被引量:2
《Journal of Energy Chemistry》2020年第2期194-208,共15页Ning Zhao Ying Zheng Jixiang Chen 
support from the National Natural Science Foundation of China(Nos.21576193 and 21176177)。
Ni–Ga alloy(Ni/Ga atomic ratio of 8),Ni3Ga and Ni5Ga3 intermetallic compounds(IMCs)catalysts were prepared from Ni–Mg-Al-Ga layered double hydroxides(LDHs)for the deoxygenation of methyl esters to hydrocarbons.In th...
关键词:Ni–Ga intermetallic compounds Methyl ester Decarbonylation/decarboxylation HYDRODEOXYGENATION C–C bond HYDROGENOLYSIS Methanation 
Adsorption and Decarbonylation Reaction of Furfural on the Pd(111) and M/Pd(111)(M=Ni, Cu and Ru) Surfaces
《Chinese Journal of Structural Chemistry》2019年第2期211-223,166,共14页XIA Sheng-Jie FANG Lei QIAN Meng-Dan MENG Yue NI Zhe-Ming 
supported by the National Natural Science Foundation of China(No.21503188)
By performing with density functional theory(DFT) method, the detailed adsorption process and the catalytic decarbonylation mechanisms of furfural over Pd(111) and M/Pd(111)(M = Ni, Cu, Ru) surfaces toward furan were ...
关键词:density functional theory FURFURAL Pd(111) bimetallic catalyst ADSORPTION decarbonylation mechanism 
Vapor Phase Decarbonylation of Furfural to Furan over Nickel Supported on SBA-15 Silica Catalysts
《Modern Research in Catalysis》2016年第3期85-94,共10页Diana Vargas-Hernández Juan Miguel Rubio-Caballero Ramon Moreno-Tost Josefa María Mérida-Robles José Santamaría-González Antonio Jiménez-López María Ana Pérez-Cruz Rosario Hernández-Huesca Pedro Maireles-Torres 
Vapor-phase transformations of furfural over SBA-15 silica supported Ni catalysts under H2 in a continuous-flow reactor at atmospheric pressure and 170°C and 230°C were investigated. Two different s...
关键词:Ni-SBA-15 FURFURAL HYDROGENATION FURAN Furfuryl Alcohol 
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