THIOESTER

作品数:23被引量:9H指数:2
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相关领域:理学医药卫生更多>>
相关作者:蒋志龙段建华黄复生徐文岳张健更多>>
相关机构:军事医学科学院第三军医大学江西师范大学更多>>
相关期刊:《Frontiers of Chemical Science and Engineering》《Open Journal of Organic Polymer Materials》《Science China Chemistry》《Chemical Research in Chinese Universities》更多>>
相关基金:国家自然科学基金更多>>
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Synthesis of poly(thiourethane-alt-thioester)by alternating ring-opening copolymerization of N-thiocarboxyanhydrides and episulfides
《Science China Chemistry》2024年第9期3091-3097,共7页Wei Xiong Tianjun Yue Haiwang Lai Chunyan Lyu Weimin Ren Hua Lu 
supported by the National Natural Science Foundation of China(22125101,22331002 to H.L.,22171037,22101040 to W.R.)。
Polythiourethanes(PTU)and polythioesters(PTE)derived from renewable sources are emerging sustainable polymers for their excellent degradability and recyclability.However,P(TU-alt-TE)copolymers have been rare and chall...
关键词:poly(thiourethane-alt-thioester) ALTERNATING ring-opening copolymerization N-thiocarboxyanhydrides episulfides 
Encouraging Solution to the Problem of Synthesizing Protein α-Thioester被引量:1
《Chinese Journal of Chemistry》2024年第10期1114-1120,共7页Xinliang Liu Zijun Gao Jie Zhao Farong Ye Ping Huang Ping Wang 
supported by the National Science Fund for Distinguished Young Scholars(22225701);the Interdisciplinary Program of Shanghai Jiao Tong University(20230102);the National Natural Science Foundation of China(22077080,92253302 and 22275122);the Shanghai Pilot Program for Basic Research Shanghai Jiao Tong University(21TQ1400210);the Special Projects of the Central Government in Guidance of Local Science and Technology Development(2021Szvup077);the China Post-doctoral Science Foundation(2023M732214).
Expressed protein ligation(EPL)provides a powerful tool to access large-size proteins with precise structures.Existing methods for constructing the critical protein thioester for EPL have predominantly relied on the r...
关键词:DESULFURIZATION GLYCOPROTEINS GLYCOPEPTIDES Protein expression Peptide thioester 
A facile approach towards high-performance poly(thioether-thioester)s with full recyclability被引量:2
《Science China Chemistry》2023年第1期251-258,共8页Jiang Dai Wei Xiong Mu-Rong Du Gang Wu Zhongzheng Cai Jian-Bo Zhu 
supported by the National Key R&D Program of China(2021YFA1501700);the National Natural Science Foundation of China(51903177,U19A2095);the“1000-Youth Talents Program”;the Fundamental Research Funds for the Central Universities(YJ201924,YJ202209)。
Developing new chemically recyclable polymers is important for a circular plastics economy.Herein,we prepared a class of 1,4-dithian-2-one(DTO)with thioether and thioester functionalities.These sulfur-substituted mono...
关键词:chemically recyclable polymer plastic polythioester ring-opening polymerization mercury adsorption 
Convenient Synthesis of Thioester-Substituted Oxindoles by Palladium-Catalyzed Thiocarbonylative Cyclization with Sulfonyl Chlorides as the Sulfur Source
《Chinese Journal of Chemistry》2023年第2期188-192,共5页Ren-Rui Xu Xiuyu Fang Xinxin Qi Xiao-Feng Wu 
We thank the financial supports from the Natural Science Foundationof Zhejiang Province(LY21B020010).
A general and straightforward strategy for the synthesis of thioester-substituted oxindoles via a palladium-catalyzed thiocarbonyla-tive cyclization process has been developed.With sulfonyl chlorides as promising sulf...
关键词:ALKENE CARBONYLATION OXINDOLES Palladium Thiocarbonylation Sulfonyl Chlorides Synthetic methods 
Palladium-catalyzed diarylative dearomatization of indoles with aryl thioesters被引量:1
《Chinese Chemical Letters》2021年第9期2765-2768,共4页Wei Huang Ming-Liang Han Yu-Wen Liu Hui Xu Hui-Xiong Dai 
the Shanghai Institute of Materia Medica;the Chinese Academy of Sciences;the National Natural Science Foundation of China(Nos.21772211 and 21920102003);the Youth Innovation Promotion Association CAS(Nos.2014229 and 2018293);the Science and Technology Commission of Shanghai Municipality(Nos.17JC1405000 and 18431907100);the Program of Shanghai Academic Research Leader(No.19XD1424600);the National Science&Technology Major Project“Key New Drug Creation and Manufacturing Program”,China(No.2018ZX09711002-006)for financial support。
We report herein a palladium-catalyzed diarylative dearomatization of indole by employing thioester and arylboronic acid as the aryl electrophiles.The reaction involved a decarbonylation/migratory insertion/terminal S...
关键词:THIOESTER DECARBONYLATION DEAROMATIZATION Indolines skeleton Diarylation 
FeCl3-6H2O-Catalyzed Synthesis of β-Ketothioesters from Chain α-Oxo Ketene Dithioactals被引量:1
《Chemical Research in Chinese Universities》2017年第5期746-752,共7页ZHAO Hui 
Supported by the Fundamental Research Funds for the Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, China(No.130028652), the Natural Science Foundation of Liaoning Province, China(No.201602002), the Foundation of Liaoning Province Education Administration, China(No.L2015003) and the National Natural Science Foundation of China(No.20902010).
A FeCl3-6H2O-catalyzed synthesis of β-ketothioesters from the hydrolysis reaction of chain α-oxoketene dithioacetals was carried out. Subsequently, we explored the FeCl3-6H2O-catalyzed Friedel-Crafts alkylation of t...
关键词:Iron(Ⅲ) chloride THIOESTER Ketene dithioacetal HYDROLYSIS Friedel-Crafts alkylation 
Recent advances in the preparation of Fmoc-SPPS-based peptide thioester and its surrogates for NCL-type reactions被引量:3
《Science China Chemistry》2017年第2期201-213,共13页Hongxing Li Suwei Dong 
supported by the Peking University Health Science Center(BMU20130354);State Key Laboratory of Natural and Biomimetic Drugs,the National Recruitment Program of Global Youth Experts(1000 Plan);the National Natural Science Foundation of China (21502005)
Solid phase peptide synthesis(SPPS)based on Fmoc chemistry has become a commonly used technique in peptide chemistry,as it can be easily conducted using automated machine,and not requiring highly toxic HF in compariso...
关键词:native chemical ligation Fmoc-SPPS peptide thioester protein chemical synthesis 
New Synthetic Route to Copoly(Ester-Thioester)s by Direct Polycondensation of Thio-Acids with Diols of Cycloketones Derivatives
《Open Journal of Organic Polymer Materials》2016年第2期76-85,共10页Nayef S. Al-Muaikel 
A new series of copoly(ester-thioester)s had been synthesized using direct polycondensation technique. These copolythioesters were synthesized by direct polycondensation of 4,4'-(tereph-thaloyIdithio) diacetic acid I,...
关键词:Synthesis Characterization Copoly(Ester-Thioester)s POLYCONDENSATION Cycloketones 
Theoretical investigations on the thiol–thioester exchange steps of different thioesters
《Chinese Chemical Letters》2015年第10期1259-1264,共6页Xiao-Hui Sun Hai-Zhu Yu Shu-Qi Pei Zhi-Min Dang 
NSFC (No. 21202006);FRFCU (No. FRF-TP14-015A2) for financial supports and Super-computer Center of Shanghai and Shenzhen for technical supports
As the rate-determining step in native chemical ligation reactions, the thiol–thioester exchange step is important in determining the efficiency of the ligations of peptides. In the present study, systematic theoreti...
关键词:Native chemical ligation Thiol–thioester exchange Density functional theory 
Effect of the Position of Reaction-Site in Amphipathic-Type Thioester in Aqueous Amidation Reaction
《Advances in Chemical Engineering and Science》2015年第3期311-316,共6页Ikumi Otomo Chiaki Kuroda 
Amphipathic-type thioesters CH3(CH2)mCOS(CH2)nCOONa (m + n = 12) were synthesized and their reaction with various alkylamines was examined. Compounds having thioester moiety close to carboxylate (m = 10, n = 2) afford...
关键词:Hydrophobic EFFECT AMIDES THIOESTERS 
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