THIOESTERS

作品数：9被引量：3H指数：1
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Palladium-catalyzed cascade Heck-type thiocarbonylation for the synthesis of functionalized thioesters
《Organic Chemistry Frontiers》2022年第5期1417-1421,共5页Ren-Rui Xu Wei Wang Xinxin Qi Xiao-Feng Wu 
We acknowledge the financial support from the Natural Science Foundation of Zhejiang Province(LY21B020010);K.C.Wong Education Foundation(GJTD-2020-08).
A palladium-catalyzed cascade Heck-type cyclization and carbonylation reaction has been developed for the synthesis of functionalized thioesters.With arylsulfonyl chlorides as odorless and readily available sulfur sou...
关键词：ESTERS catalyzed synthesis 
Palladium-catalyzed diarylative dearomatization of indoles with aryl thioesters被引量：1
《Chinese Chemical Letters》2021年第9期2765-2768,共4页Wei Huang Ming-Liang Han Yu-Wen Liu Hui Xu Hui-Xiong Dai 
the Shanghai Institute of Materia Medica;the Chinese Academy of Sciences;the National Natural Science Foundation of China(Nos.21772211 and 21920102003);the Youth Innovation Promotion Association CAS(Nos.2014229 and 2018293);the Science and Technology Commission of Shanghai Municipality(Nos.17JC1405000 and 18431907100);the Program of Shanghai Academic Research Leader(No.19XD1424600);the National Science&Technology Major Project“Key New Drug Creation and Manufacturing Program”,China(No.2018ZX09711002-006)for financial support。
We report herein a palladium-catalyzed diarylative dearomatization of indole by employing thioester and arylboronic acid as the aryl electrophiles.The reaction involved a decarbonylation/migratory insertion/terminal S...
关键词：THIOESTER DECARBONYLATION DEAROMATIZATION Indolines skeleton Diarylation 
Theoretical investigations on the thiol–thioester exchange steps of different thioesters
《Chinese Chemical Letters》2015年第10期1259-1264,共6页Xiao-Hui Sun Hai-Zhu Yu Shu-Qi Pei Zhi-Min Dang 
NSFC (No. 21202006);FRFCU (No. FRF-TP14-015A2) for financial supports and Super-computer Center of Shanghai and Shenzhen for technical supports
As the rate-determining step in native chemical ligation reactions, the thiol–thioester exchange step is important in determining the efficiency of the ligations of peptides. In the present study, systematic theoreti...
关键词：Native chemical ligation Thiol–thioester exchange Density functional theory 
Effect of the Position of Reaction-Site in Amphipathic-Type Thioester in Aqueous Amidation Reaction
《Advances in Chemical Engineering and Science》2015年第3期311-316,共6页Ikumi Otomo Chiaki Kuroda 
Amphipathic-type thioesters CH3(CH2)mCOS(CH2)nCOONa (m + n = 12) were synthesized and their reaction with various alkylamines was examined. Compounds having thioester moiety close to carboxylate (m = 10, n = 2) afford...
关键词：Hydrophobic EFFECT AMIDES THIOESTERS 
Theoretical study on formation of thioesters via O-to-S acyl transfer被引量：1
《Science China Chemistry》2012年第10期2075-2080,共6页WANG Chen GUO Qing-Xiang 
support to the study by the National Natural Science Foundation of China (20932006)
Peptide thioester preparation via intramolecular O-to-S acyl transfer is a recently developed method for protein chemical synthesis through Fmoc chemistry. Theoretical calculations have been carried out to study the m...
关键词：density functional theory native chemical ligation THIOESTER O-to-S acyl transfer HYDROLYSIS 
Partially purified Carica papaya lipase： a versatile biocatalyst for the hydrolytic resolution of （R,S）-2-arylpropionic thioesters in water-saturated organic solvents
《中国生物学文摘》2007年第2期4-4,共1页Ng, I. S. Tsai, S. W. 
关键词：番木瓜脂肪酶 生物催化剂 水解作用 (R S)-2-芳香基丙酸硫酯 溶剂 
A Stereoselective Approach to S-Vinyl Thioesters from Alkynes,Elemental Sulfur and Acyl Chlorides
《Chinese Chemical Letters》2000年第1期1-2,共2页Jun Hua WANG Qing Xu Xian HUANG Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou 310028 
A facile, stereoselective synthesis of S-vinyl thioesters from easily available starting compounds and reagents is showed.
关键词：S-vinyl thioesters HYDROZIRCONATION 
A New Entry to γ-Butenolides and trans-α,β-unsaturated Thioesters
《厦门大学学报（自然科学版）》1999年第S1期542-542,共1页
关键词：UNSATURATED A New Entry to 
Reductive Cleavage of S-S Bond by Samarium Diiodide: Synthesis of β-Thioesters and β-Thionitriles被引量：1
《Chinese Chemical Letters》1999年第1期7-8,共2页Hua Jiang JIANG Yong Min ZHANG(Department of Chemistry, Hangzhou University, Hangzhou, Zhejiang, 310028) 
The reduction of disulfides by samarium diiodide led to sa arium thiolates (ArSSml2).This new thiolate anion species reacted smoothly with α, β -unsaturated esters (nitriles) to give 1,4-addition products β -thioes...
关键词：β-thioesters β-thionitriles samarium diiodide synth esis 
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