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financial support from the National Natural Science Foundation of China(No.22208279);Financial support from the Fuzhou University(No.0041/511095)。
A visible light-promoted fast photochemical Wolff rearrangement was developed toward synthesis ofα-substituted amides in continuous flow with the use of a photochemical oscillatory flow reactor(POFR).The control expe...
funding from the European Union's Horizon 2022 research and innovation program under the Marie Skłodowska-Curie grant agreement(No.101104138 to W.C.);support from the Fund for Scientific Research Flanders(FWO–grant No.1246922 N).
Ketene and its derivatives,including surface acetate and acylium ion,are pivotal intermediates in zeolite catalysis,facilitating the conversion of C1 molecules into various chemicals.Understanding the formation,transf...
supported by the National Natural Science Foundation of China(21822103,21820102003,91956201);the Program of Introducing Talents of Discipline to Universities of China(111Program,B17019);the Natural Science Foundation of Hubei Province(2017AHB047);Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis。
Concise synthesis of eight-membered lactones,a kind of medium-sized heterocycles widespread in many bioactive natural products,is highly significant.However,it still remains a challenge due to unfavorable entropic fac...
supported by the“Fundamental Research Funds for the Central Universities”(Nos.21620318,2019QNGG22);“the Open Fund of Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications”(No.2020B121201005).
A low-cost manganese-catalyzed oxidant-free selective C–H acylation of indole with ketene is reported.This protocol features mild reaction conditions and good functional group tolerance.The yield is from middle to ex...
This work was supported by the National Natural Science Foundation of China(21971262,92056201);the National Postdoctoral Program for Innovative Talents(BX20190399);Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery(2019B030301005);the National Mega-project for Innovative Drugs(2019ZX09721001-006-001);the Program for Guangdong Introducing Innovative and Entrepreneurial Teams(2016ZT06Y337);the Fundamental Research Funds for the Central Universities(20ykpy113,18843407).
An unprecedented gold-catalyzed ketene C=O/C=C bifunctionalization method has been developed.Mechanistic studies and density function theory(DFT)calculations indicate that the reaction is initiated by gold-catalyzed W...
supported by “Fondazione Cassa Risparmio Perugia” (Project 2015.0331.021 Scientific & Technological Research);EC COST Action CM1404 (Chemistry of Smart Energy Carriers and Technologies– SMARTCATS);the Università degli Studi di Perugia (“Fondo Ricerca di Base 2017”);Italian MIUR and Università degli Studi di Perugia within the program“Department of Excellence-2018-2022-project AMIS”
Detailed understanding of the mechanism of the combustion relevant multichannel reactions of O(3P) with unsaturated hydrocarbons (UHs) requires the identification of all primary reaction products, the determination of...
National Natural Science Foundation of China(No.31370578);State Key Laboratory of Pulp and Paper Engineering,China(No.201508)
The charge density of cellulose fibers is a key parameter in the papermaking systems,and this is particularly true for the Alkyl Ketene Dimer( AKD) paper sizing.Zeta potential and cationic demand are often used to cha...
Supported by the Fundamental Research Funds for the Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, China(No.130028652), the Natural Science Foundation of Liaoning Province, China(No.201602002), the Foundation of Liaoning Province Education Administration, China(No.L2015003) and the National Natural Science Foundation of China(No.20902010).
A FeCl3-6H2O-catalyzed synthesis of β-ketothioesters from the hydrolysis reaction of chain α-oxoketene dithioacetals was carried out. Subsequently, we explored the FeCl3-6H2O-catalyzed Friedel-Crafts alkylation of t...
Internet has now become the main place of IT technology and business innovations, from Web 2.0, social network, mobile Internet, cloud computing, to Internet of Things and big data. To embrace these innova- tions as w...
The selectivities, including peri-, regio-, and diastereoselectivities, in the Staudinger reaction involving vicinal diimines and ketenes were investigated theoretically via the density functional theory (DFT) calcu...