1-金刚烷基甲基丙烯酸酯的合成研究  

Study on synthesis of 1-adamantyl methacrylate

作　　者：陈曦 孙芳[1,2] CHEN Xi;SUN Fang(College of Chemistry,Beijing University of Chemical Technology,Beijing 100029,China;Anqing Research Institute,Beijing University of Chemical Technology,Anqing,246000,Anhui,China)

机构地区：[1]北京化工大学化学学院,北京100029 [2]北京化工大学安庆研究院,安徽安庆246000

出　　处：《粘接》2022年第5期1-4,共4页Adhesion

基　　金：国家自然科学基金项目(项目编号:52073018)。

摘　　要：以甲基丙烯酰氯和1-金刚烷醇为原料,二氯甲烷为溶剂,采用酯化方法合成了1-金刚烷基甲基丙烯酸酯(ADMA),研究反应温度、反应时间、缚酸剂用量以及原料配比对ADMA收率的影响。结果表明:甲基丙烯酰氯与1-金刚烷醇物质的量比为1.5∶1,阻聚剂吩噻嗪和缚酸剂三乙胺质量分数分别为1.2%、49.4%,反应温度、反应时间分别为30℃、21 h为最佳反应条件,ADMA的收率为86.5%。1-adamantyl methacrylate(ADMA)was synthesized by the esterification reaction of methacryloyl chloride with 1-adamantol,and methylene chloride was used as the solvent.The effects of reaction temperature,reaction time,the deacid reagent and raw material ratio on the yield of ADMA were studied in detail.The results showed that the molar ratio of methacryloyl chloride to 1-adamantol was 1.5∶1,the mass percent of polymerization inhibitor phenothiazine and the deacid reagent triethylamine were 1.2% and 49.4%,respectively,the reaction temperature and time were 30℃ and 21 h respectively for Under the optimum reaction conditions,with the yield of ADMA reached 86.5%.

关 键 词：光刻胶 酯化 金刚烷醇 1-金刚烷基甲基丙烯酸酯 缚酸剂 

分 类 号：O621.3[理学—有机化学]