Preparation of aldoxime through direct ammoximation using titanium silicalite-1 catalyst  

作　　者：Zhigang Xu Xiongfei Jin Tao Zhou Qian Zou Longcheng Liu zhongbo Wang Hanbing Sheng Huasheng Xie 

机构地区：[1]Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources,College of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China [2]Kopperchem Industry Corp.,LTD,Solvent Extraction Engineering Research Center,Chongqing 401221,China [3]Cangzhou Dahua Group Co.,Ltd.,Cangzhou 061000,China

出　　处：《Chinese Journal of Chemical Engineering》2022年第7期11-17,共7页中国化学工程学报（英文版）

基　　金：the National Natural Science Foundation of China(21376269);the Hunan Provincial Science and Technology Plan,China (2016TP1007);the independent exploration and innovation project for graduate students of Central South University(2020zzts403)

摘　　要：The liquid phase direct ammoximation of 5-isooctyl salicylaldehyde with ammonia and hydrogen peroxide was studied using titanium silicalite-1(TS-1)catalyst.The effect of reaction parameters on the yield of the product was studied,which include reaction temperature,reaction time,molar ratio of ammonia to aldehyde as well as hydrogen peroxide to aldehyde.The influence of the amount of catalyst on the reaction results was also investigated.The maximum 5-isooctyl salicylaldoxime yield of 98.76%was achieved under the following optimal reaction conditions:the molar ratio of 5-isooctylaldehyde to hydrogen peroxide and ammonia of 1:1.4:1.6,the reaction temperature of 70℃,the amount of TS-1 of 17.5 g·mol^(-1)(5-isooctyl salicylaldehyde),and the feeding time of 2 h.This method has the mild reaction conditions and avoids the shortcomings of traditional methods.Moreover,useless inorganic salts by-products are avoided,and there is no environmental pollution.

关 键 词：Titanium silicalite-1 AMMOXIMATION ALDOXIME EXTRACTANT Process optimization 

分 类 号：O621.251[理学—有机化学]