AMMOXIMATION

作品数:6被引量:14H指数:2
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相关期刊:《Chinese Journal of Chemical Engineering》《China Petroleum Processing & Petrochemical Technology》《National Science Review》《Transactions of Tianjin University》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划更多>>
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Chemical and engineering bases for green H_(2)0_(2) production and related oxidation and ammoximation of olefins and analogues
《National Science Review》2024年第8期298-315,共18页Minghua Qiao Xingui Zhou Zexue Du Peng Wu Baoning Zong 
supported by the State Key Research and Development Project of China (2021YFA1501400).
Plastics,fibers and rubber are three mainstream synthetic materials that are essential to our daily lives and contribute significantly to the quality of our lives.The production of the monomers of these synthetic poly...
关键词:hydrogen peroxide OXIDATION AMMOXIMATION propylene oxide EPICHLOROHYDRIN cyclohexanone oxime 
Preparation of aldoxime through direct ammoximation using titanium silicalite-1 catalyst被引量:1
《Chinese Journal of Chemical Engineering》2022年第7期11-17,共7页Zhigang Xu Xiongfei Jin Tao Zhou Qian Zou Longcheng Liu zhongbo Wang Hanbing Sheng Huasheng Xie 
the National Natural Science Foundation of China(21376269);the Hunan Provincial Science and Technology Plan,China (2016TP1007);the independent exploration and innovation project for graduate students of Central South University(2020zzts403)
The liquid phase direct ammoximation of 5-isooctyl salicylaldehyde with ammonia and hydrogen peroxide was studied using titanium silicalite-1(TS-1)catalyst.The effect of reaction parameters on the yield of the product...
关键词:Titanium silicalite-1 AMMOXIMATION ALDOXIME EXTRACTANT Process optimization 
Effect of Extra-Framework Titanium in TS-1 on the Ammoximation of Cyclohexanone被引量:1
《Transactions of Tianjin University》2017年第3期230-236,共7页Yaquan Wang Shuhai Wang Teng Zhang Jiaxin Ye Xiao Wang Dali Wang 
was supported by the National Basic Research Program of China(‘‘973’’Program,No.G2000048005);the National Natural Science Foundation of China(No.21276183)
Titanium silicalite (TS-1) without and with extra-framework titanium have been prepared and TiO2is also prepared under the same conditions. All the samples are characterized with XRD, FT-IR, and UV–Vis. The effects o...
关键词:Network function virtualization Titanium dioxide 
Deactivation Behavior of Hollow Titanium Silicalite Zeolite in Aqueous Ammonia Solution under Simulated Industrial Cyclohexanone Ammoximation Conditions被引量:2
《China Petroleum Processing & Petrochemical Technology》2016年第4期1-10,共10页Xia Changjiu Lin Min Peng Xinxin Zhu Bin Xu Guangtong Shu Xingtian 
financially supported by the National Basic Research Program of China(973 Program,2006CB202508);the China Petrochemical Corporation(SINOPEC Group 20673054)
For simulating the real deactivation of hollow titanium silicalite(HTS) zeolite in commercial ammoximation process, HTS was treated by 10% NH_3·H_2O solution at 120 ℃ in stirred autoclave. It is found that a part of...
关键词:deactivation hollow titanium silicate ammoximation extraframework Ti TEM 
AmmAmmoximation of Cyclohexanone to Cyclohexanone Oxime Catalyzed by Titanium Silicalite-1 Zeolite in Three-phase System被引量:7
《Chinese Journal of Chemical Engineering》2012年第5期889-894,共6页刘国清 吴剑 罗和安 
Supported by the National Natural Science Foundation of China and Sinopec (20736009)
An innovative green process of producing ε-caprolactam was proposed by integrating ammoximation and Beckmann rearrangement effectively. As a first part of the new process, TS-1 molecular sieve-catalyzed synthesis of ...
关键词:AMMOXIMATION molecular sieve TS-1 cyclohexanone oxime CYCLOHEXANE three-phase system 
Kinetics of Cyclohexanone Ammoximation over Titanium Silicate Molecular Sieves被引量:3
《Chinese Journal of Chemical Engineering》2005年第1期32-36,共5页李永祥 吴巍 闵恩泽 
SupportedbytheMajorStateBasicResearchDevelopmentProgramofChina(G20000480-5).
An intrinsic kinetics of cyclohexanone ammoximation in the liquid phase over titanium silicate molecular sieves is investigated in an isothermal slurry reactor at different initial reactant concentrations, catalyst lo...
关键词:KINETICS titanium silicalite CYCLOHEXANONE AMMOXIMATION cyclohexanone oxime 
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