financially supported by the National Natural Science Foundation of China(22205205,22472151);the Zhejiang Provincial Natural Science Foundation of China(LQ22B030008);the Science Foundation of Zhejiang Sci-Tech University(ZSTU)under Grant No.21062337-Y.
Constructing electrocatalytic overall reaction technology to couple the electrosynthesis of adipic acid with energy-saving hydrogen production is of significant for sustainable energy systems.However,the development o...
financially supported by the National Natural Science Foundation of China(22222806,22178162,and 22072065);the Distinguished Youth Foundation of Jiangsu Province(BK20220053);the Six Talent Peaks Project in Jiangsu Province(JNHB035)。
The selective oxidation of cyclohexane is a promising green route for the production of KA oil(cyclohexanol and cyclohexanone),but remains a huge challenge to design high-performing heterogeneous catalysts under mild ...
supported by the Chair of Inorganic Molecular Chemistry(TU Dresden)by Prof.Dr.Jan J.Weigand.Evonik AG provided the silica carrier material Aerosil380 for research purposes;The Federal State of Saxony(Germany)funded the first author’s work through the Saxon State Scholarship Program;The corresponding author thanks German Research Foundation(DFG)for funding of project SE 2450/2-1(Nbr.507997100).
Replacing fossil carbon sources with green bio-oils is a promising route to switch to a sustainable chemical industry,although their high oxygen contents are challenging.Catalytic hydrodeoxygenation is a favored route...
the National Natural Science Foundation of China(Nos.22293012,22121002,22179132)。
The challenge of breaking 5-5'bonds in lignin,attributed to their high bonding energy,has prompted the development of a new transformation pathway.Biphenyl,an important model compound for lignin,contains these 5-5'bon...
the support from Clariant International Ltd.;the National Natural Science Foundation of China (Nos.22022811,21938008,and U21B2096);the Haihe Laboratory of Sustainable Chemical Transformations。
The dehydrogenation of cyclohexanol to cyclohexanone is a crucial industrial process in the production of caprolactam and adipic acid, both of which serve as important precursors in nylon textiles. This endothermic re...
Financial supports from the State Key Laboratory of Catalytic Materials and Reaction Engineering (RIPP, SINOPEC)。
The promoting effect of zirconium addition on Pd/Beta catalysts has been investigated in the selective hydrogenation of phenol to cyclohexanone in the aqueous phase. The activity of the catalyst in the reaction was gr...
This work was supported by Financial support from the National Natural Science Foundation of China(21908189,21872121);the National Key R&D Program of China(2016YFA0202900);the Key Program supportedby theNaturalScience Foundationof ZhejiangProvince,China(LZ18B060002);the Key R&D Project of Zhejiang Province(2020C01133).
Selective hydrogenation of phenol to cyclohexanone is intriguing in chemical industry.Though a few catalysts with promising performances have been developed in recent years,the basic principle for catalyst design is s...
supported by Key Research and Development Program in Hunan Province(Grant No.2019GK2041);Hunan Provincial Natural Science Foundation of China(Grant No.2019JJ50579);Scientific Research Fund of Hunan Provincial Education Department(Grant Nos.18C0106 and 20B550);the fund of the Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education&Hubei Key Laboratory of Catalysis and Materials Science(Grant No.CHCL21004);National Training Program of Innovation and Entrepreneurship for Undergraduates(Grant No.S202010530022);and Hunan Key Laboratory of Environment Friendly Chemical Process Integrated Technology and Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization.
The one-step highly selective oxidation of cyclohexane into cyclohexanone and cyclohexanol as the essential intermediates of nylon-6 and nylon-66 is considerably challenging.Therefore,an efficient and low-cost catalys...
The financial supports from the National Natural Science Foundation(21776127,21921006);the Jiangsu Province Key R&D Program(BE2018009-2);the Jiangsu Province natural science research of College and university general project(20KJB540003);a project funded by the priority academic program development of Jiangsu higher education institutions(PAPD);the State Key Laboratory of Materials-Oriented Chemical Engineering(ZK201902);the outstanding young teacher’s project of Changzhou Vocational Institute of Textile and Garment of China。
Phenol hydrogenation is a green route to prepare cyclohexanone,an intermediate for the production of nylon 66 and nylon 6.The development of high-performance catalysts still keeps a great challenge.Herein,the activate...
supported by the National Natural Science Foundation of China(No.22073081);the Fundamental Research Funds for the Central Universities.
ε-Caprolactone is traditionally produced through Baeyer-Villiger oxidation of cyclohexanone oxidized by peracids in industry,which inevitably results in large discard acid and environmental pollution.To this end,a gr...