CYCLOHEXANONE

作品数:78被引量:79H指数:5
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相关领域:理学更多>>
相关作者:雷蓓樊永惠胡岚杨彩宁张敏更多>>
相关机构:西安近代化学研究所中国石油化工股份有限公司浙江大学沈阳工业大学更多>>
相关期刊:《China Petroleum Processing & Petrochemical Technology》《Transactions of Tianjin University》《Progress in Natural Science:Materials International》《Chinese Journal of Catalysis》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划山西省自然科学基金中国博士后科学基金更多>>
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Nickel-copper alloying arrays realizing efficient co-electrosynthesis of adipic acid and hydrogen
《Journal of Energy Chemistry》2025年第2期7-15,I0001,共10页Xuhui Ren Qianyu Zhang Yun Tong Guorong Zhou Cong Lin Yanying Zhao Pengzuo Chen 
financially supported by the National Natural Science Foundation of China(22205205,22472151);the Zhejiang Provincial Natural Science Foundation of China(LQ22B030008);the Science Foundation of Zhejiang Sci-Tech University(ZSTU)under Grant No.21062337-Y.
Constructing electrocatalytic overall reaction technology to couple the electrosynthesis of adipic acid with energy-saving hydrogen production is of significant for sustainable energy systems.However,the development o...
关键词:Cu_(0.81)Ni_(0.19)alloy Adipic acid Hydrogen fuel Cyclohexanone oxidation reaction Hydrogen evolution reaction 
Highly dispersive tetrahedral vanadium species on pure silica ZSM-12 zeolite boosting the selective oxidation of cyclohexane into cyclohexanone
《Science China Chemistry》2024年第7期2206-2214,共9页Menglin Xie Ting Li Chao Wu Xiaoling Liu Jinling Ni Siqin Yao Yu Zhou Shibo Xi Jun Wang 
financially supported by the National Natural Science Foundation of China(22222806,22178162,and 22072065);the Distinguished Youth Foundation of Jiangsu Province(BK20220053);the Six Talent Peaks Project in Jiangsu Province(JNHB035)。
The selective oxidation of cyclohexane is a promising green route for the production of KA oil(cyclohexanol and cyclohexanone),but remains a huge challenge to design high-performing heterogeneous catalysts under mild ...
关键词:ZEOLITE metal doping cyclohexane oxidation heterogeneous catalysis 
Controlling the reaction network of Ni/silica derived conversion of bio-oil surrogate guaiacol
《Carbon Resources Conversion》2024年第1期39-60,共22页Nils Kretzschmar Oliver Busse Markus Seifert 
supported by the Chair of Inorganic Molecular Chemistry(TU Dresden)by Prof.Dr.Jan J.Weigand.Evonik AG provided the silica carrier material Aerosil380 for research purposes;The Federal State of Saxony(Germany)funded the first author’s work through the Saxon State Scholarship Program;The corresponding author thanks German Research Foundation(DFG)for funding of project SE 2450/2-1(Nbr.507997100).
Replacing fossil carbon sources with green bio-oils is a promising route to switch to a sustainable chemical industry,although their high oxygen contents are challenging.Catalytic hydrodeoxygenation is a favored route...
关键词:HYDRODEOXYGENATION Design of experiments BIO-OIL Nickel silica catalyst Continuous mode flow reactor KA-oil CYCLOHEXANOL CYCLOHEXANONE 
Robust Carbon-Carbon Cleavage in Lignin to Produce Phenol and Cyclohexanone
《Chemical Research in Chinese Universities》2024年第1期29-35,共7页WANG Lulin CHENG Xiaomeng DONG Minghua LUAN Sen WU Yuxuan HAN Buxing LIU Huizhen 
the National Natural Science Foundation of China(Nos.22293012,22121002,22179132)。
The challenge of breaking 5-5'bonds in lignin,attributed to their high bonding energy,has prompted the development of a new transformation pathway.Biphenyl,an important model compound for lignin,contains these 5-5'bon...
关键词:LIGNIN 5-5'Bond Ni/SiO_(2) PHENOL 
Progress in Processes and Catalysts for Dehydrogenation of Cyclohexanol to Cyclohexanone
《Transactions of Tianjin University》2023年第3期196-208,共13页Jing Gong Shixin Hou Yue Wang Xinbin Ma 
the support from Clariant International Ltd.;the National Natural Science Foundation of China (Nos.22022811,21938008,and U21B2096);the Haihe Laboratory of Sustainable Chemical Transformations。
The dehydrogenation of cyclohexanol to cyclohexanone is a crucial industrial process in the production of caprolactam and adipic acid, both of which serve as important precursors in nylon textiles. This endothermic re...
关键词:CYCLOHEXANOL DEHYDROGENATION CYCLOHEXANONE Copper-based catalyst Reaction coupling processes 
The critical role of Zr in controlling the activity of Pd/Beta on the hydrogenation of phenol to cyclohexanone
《Chinese Journal of Chemical Engineering》2023年第5期79-87,共9页Bin Gao Junwen Chen Qi Zuo Hongyan Wang Wenlin Li 
Financial supports from the State Key Laboratory of Catalytic Materials and Reaction Engineering (RIPP, SINOPEC)。
The promoting effect of zirconium addition on Pd/Beta catalysts has been investigated in the selective hydrogenation of phenol to cyclohexanone in the aqueous phase. The activity of the catalyst in the reaction was gr...
关键词:PALLADIUM Phenol hydrogenation CYCLOHEXANONE ZIRCONIUM ZEOLITE 
Towards the selectivity distinction of phenol hydrogenation on noble metal catalysts
《Nano Materials Science》2023年第1期91-100,共10页Shanjun Mao Zhe Wang Zhirong Chen Kejun Wu Kaichao Zhang Qichuan Li Huihuan Yan Guofeng Lü Guodong Huang Yong Wang 
This work was supported by Financial support from the National Natural Science Foundation of China(21908189,21872121);the National Key R&D Program of China(2016YFA0202900);the Key Program supportedby theNaturalScience Foundationof ZhejiangProvince,China(LZ18B060002);the Key R&D Project of Zhejiang Province(2020C01133).
Selective hydrogenation of phenol to cyclohexanone is intriguing in chemical industry.Though a few catalysts with promising performances have been developed in recent years,the basic principle for catalyst design is s...
关键词:PHENOL Selective hydrogenation CYCLOHEXANONE DFT Noble metal catalysts 
Ultrasound-assisted co-precipitation synthesis of mesoporous Co_(3)O_(4)–CeO_(2)composite oxides for highly selective catalytic oxidation of cyclohexane被引量:2
《Frontiers of Chemical Science and Engineering》2022年第8期1211-1223,共13页Shangjun Fu Kuiyi You Zhenpan Chen Taobo Liu Qiong Wang Fangfang Zhao Qiuhong Ai Pingle Liu He’an Luo 
supported by Key Research and Development Program in Hunan Province(Grant No.2019GK2041);Hunan Provincial Natural Science Foundation of China(Grant No.2019JJ50579);Scientific Research Fund of Hunan Provincial Education Department(Grant Nos.18C0106 and 20B550);the fund of the Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education&Hubei Key Laboratory of Catalysis and Materials Science(Grant No.CHCL21004);National Training Program of Innovation and Entrepreneurship for Undergraduates(Grant No.S202010530022);and Hunan Key Laboratory of Environment Friendly Chemical Process Integrated Technology and Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization.
The one-step highly selective oxidation of cyclohexane into cyclohexanone and cyclohexanol as the essential intermediates of nylon-6 and nylon-66 is considerably challenging.Therefore,an efficient and low-cost catalys...
关键词:Co_(3)O_(4)–CeO_(2)composite oxides CYCLOHEXANONE CYCLOHEXANOL ultrasonic-assisted co-precipitation selective oxidation solvent-free 
Nb_(2)O_(5)promoted Pd/AC catalyst for selective phenol hydrogenation to cyclohexanone被引量:1
《Chinese Journal of Chemical Engineering》2022年第4期87-93,共7页Chunhua Zhang Zhengyan Qu Hong Jiang Rizhi Chen Weihong Xing 
The financial supports from the National Natural Science Foundation(21776127,21921006);the Jiangsu Province Key R&D Program(BE2018009-2);the Jiangsu Province natural science research of College and university general project(20KJB540003);a project funded by the priority academic program development of Jiangsu higher education institutions(PAPD);the State Key Laboratory of Materials-Oriented Chemical Engineering(ZK201902);the outstanding young teacher’s project of Changzhou Vocational Institute of Textile and Garment of China。
Phenol hydrogenation is a green route to prepare cyclohexanone,an intermediate for the production of nylon 66 and nylon 6.The development of high-performance catalysts still keeps a great challenge.Herein,the activate...
关键词:Phenol hydrogenation CYCLOHEXANONE Nb_(2)O_(5) PD/AC ACIDITY 
One-pot Baeyer-Villiger oxidation of cyclohexanone with in situ generated hydrogen peroxide over Sn-Beta zeolites
《Green Chemical Engineering》2021年第3期294-300,共7页Jianwei Luo Haoran Yuan Hui Liu Jingbo Li Yu Wang Yong Wang Jia Yao Haoran Li 
supported by the National Natural Science Foundation of China(No.22073081);the Fundamental Research Funds for the Central Universities.
ε-Caprolactone is traditionally produced through Baeyer-Villiger oxidation of cyclohexanone oxidized by peracids in industry,which inevitably results in large discard acid and environmental pollution.To this end,a gr...
关键词:Baeyer-Villiger oxidation Ε-CAPROLACTONE Sn-Beta Hydrogen peroxide Molecular oxygen 
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