甘油/CO_(2)合成碳酸甘油酯的研究进展  

Research Progress in Synthesis of Glycerol Carbonate From Glycerol and CO_(2)

作　　者：乔枫瑞 李若萱 邱成鹏 牛紫嫣 王晋 王潇潇[1] 潘瑞丽[1] 钱成 刘振民[1] QIAO Feng-rui;LI Ruo-xuan;QIU Cheng-peng;NIU Zi-yan;WANG Jin;WANG Xiao-xiao;PAN Rui-li;QIAN Cheng;LIU Zhen-min(School of Chemistry and Biological Engineering,Taiyuan University of Science and Technology,Taiyuan Shanxi 030024,China;PetroChina Southwest Oil and Gas Field Company,Chengdu Sichuan 61000,China)

机构地区：[1]太原科技大学化学与生物工程学院,山西太原030024 [2]中国石油西南油气田公司,四川成都610000

出　　处：《当代化工》2022年第7期1683-1686,共4页Contemporary Chemical Industry

基　　金：山西省青年科学基金(项目编号:201601D202016);山西省高等学校科技创新项目(项目编号:2020L0366);山西省高等学校大学生创新创业训练项目(项目编号:2020359);太原科技大学大学生创新创业训练项目(项目编号:XJ2019107、XJ2020043、XJ2020045)。

摘　　要：碳酸甘油酯是一种高附加值的甘油衍生物,以甘油与CO_(2)为原料合成碳酸甘油酯已成为实现生物柴油副产物甘油和温室气体CO_(2)综合利用的有效途径之一。总结了甘油/CO_(2)法合成碳酸甘油酯的热力学分析,认为采用耦合反应是实现该合成过程的有效方法。详细阐述了无机/有机碱催化剂、离子液体催化剂、单组分金属氧化物催化剂、复合氧化物催化剂和负载型固体碱催化剂对碳酸甘油酯合成及其反应活性的影响。最后对碳酸甘油酯的应用进行了展望。Glycerol carbonate is a kind of glycerol derivative with high added value. The preparation of glycerol carbonate with glycerol and CO_(2)has become one of the effective ways to realize the comprehensive utilization of biodiesel by-product glycerol and greenhouse gas CO_(2). Based on the thermodynamics analysis, it is found that the reaction of glycerol with CO_(2)is not feasible in thermodynamics, however, the coupling reaction is the effective method to promote the synthesis process. The influence of the used catalysts on glycerol carbonate synthesis and reactivity was summarized. These catalysts include the inorganic/organic alkali catalyst, ionic liquid catalyst,one-component catalyst, compound oxide catalyst and metal oxide catalyst supported solid base catalysts. Finally, the application of glycerol carbonate was also prospected.

关 键 词：甘油 二氧化碳 碳酸甘油酯 热力学 催化剂 

分 类 号：TQ645[化学工程—精细化工]