Engaging Yne-Allenes in Cycloaddition Reactions: Recent Developments  

作　　者：Jia-Yin Wang Wen-Juan Hao Shu-Jiang Tu Bo Jiang 

机构地区：[1]School of Chemistry&Materials Science,Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials,Jiangsu Normal University,Xuzhou,Jiangsu 221116,China

出　　处：《Chinese Journal of Chemistry》2022年第10期1224-1242,共19页中国化学（英文版）

基　　金：We are grateful for financial support from the National Natural ScienceFoundation of China(Nos.21871112 and 21971090).

摘　　要：Yne-allenes bearing both a C-C triple bond and an allene unit are a class of focal substrates in organic synthesis,in view of their structure diversity,.high reactivity and intermediate variety in the past years.Engaging yne-allenes in numerous annulation cascades provides efficient and direct accesses to elaborate functionalized polycyclic molecular architectures in a convergent manner.There are lots of types of catalytic chemical reactions such as intramolecular cyclizations,cycloisomerizations,intermolecular annulations,and bicyclizations as well as tricyclizations with the assistance of Lewis acids,Bronsted acids,bases,transition metals,and otherr c atalysts.This review provides an overview of the chemistry developed with transformations of yne-allenes by discussing their general and specific reactivities,presenting and commenting on their mechanisms as well as their applications.

关 键 词：Yne-alenes CYCLOADDITION Domino reactions CARBOCYCLES HETEROCYCLES 

分 类 号：O64[理学—物理化学]