CARBOCYCLES

作品数：10被引量：5H指数：1
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相关领域：理学更多>>
相关作者：姜波更多>>
相关机构：江苏师范大学河南大学更多>>
相关期刊：《Science China Chemistry》《Science Bulletin》《Research》《National Science Review》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划国家教育部博士点基金更多>>
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Photocatalytic[3+2]Cycloaddition of Alkyl/aryl Iodides and Internal Alkynes by Merging Halogen and Hydrogen Atom Transfer
《Chinese Journal of Chemistry》2024年第19期2329-2334,共6页Zhenyu Gu Rong Jia Tianqing Zeng Hanliang Zheng Gangguo Zhu 
supported by the Natural Science Foundation of Zhejiang Province(LZ20B020001 and LY23B020004);the Ten Thousand Talents Plan of Zhejiang Province(2020R52021);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang Province(2022R01007);the National Natural Science Foundation of China(22371262,22071218,and 22203076).
Comprehensive Summary A visible light photocatalytic[3+2]cycloaddition of alkynes with readily accessible organic iodides as the C3 synthon is developed herein.By merging halogen atom transfer(XAT)and hydrogen atom tr...
关键词：Photocatalysis Halogen atom transfer Hydrogen atom transfer [3+2]cycloaddition CYCLOPENTANE Carbocycles Radical reactions DIASTEREOSELECTIVITY 
Catalytic enantioselective domino alkenylation-alkynylation of alkenes: stereoselective synthesis of 5–7 membered azacycles and carbocycles
《Science China Chemistry》2023年第6期1701-1706,共6页Zhaoming Ma Lantian Sun Jianrong Steve Zhou 
supported by the National Natural Science Foundation of China(22271007);the Peking University Shenzhen Graduate School;the State Key Laboratory of Chemical Oncogenomics;the Guangdong Provincial Key Laboratory of Chemical Genomics;the Shenzhen Bay Laboratory and Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs for JSZ。
Enantioselective domino alkenylation-alkynylation of olefins is achieved for the first time,using terminal alkynes directly as pronucleophiles.The new reaction enables facile construction of azacycles carrying quatern...
关键词：membered cycles synthesis 
Dancing on Ropes-Enantioselective Functionalization of Preformed Four-Membered Carbocycles被引量：1
《Chinese Journal of Chemistry》2022年第11期1346-1358,I0002,共14页Jun Chen Qiang Zhou Huayi Fang Ping Lu 
We are grateful for the financial support from the National Natural Science Foundation of China(22071028,21772024,21921003 to P.L.;21801044,22071122 to H.F.);We thank Dr.Huize Jing for her work on illustrations of rope acrobatics.
Cyclobutane derivatives have been recognized as useful structural motifs in organic synthesis and drug design.With the revival of photochemistry,the enantioselective synthesis of cyclobutane derivatives using[2+2]-cyc...
关键词：Enantioselective functionalization Strained molecules Density functional calculations Strain-releasing C-H activation 
Engaging Yne-Allenes in Cycloaddition Reactions: Recent Developments被引量：1
《Chinese Journal of Chemistry》2022年第10期1224-1242,共19页Jia-Yin Wang Wen-Juan Hao Shu-Jiang Tu Bo Jiang 
We are grateful for financial support from the National Natural ScienceFoundation of China(Nos.21871112 and 21971090).
Yne-allenes bearing both a C-C triple bond and an allene unit are a class of focal substrates in organic synthesis,in view of their structure diversity,.high reactivity and intermediate variety in the past years.Engag...
关键词：Yne-alenes CYCLOADDITION Domino reactions CARBOCYCLES HETEROCYCLES 
Gold Self-Relay Catalysis Enabling[3,3]-Sigmatropic Rearrange-ment/Nazarov Cyclization and Allylic Alkylation Cascade for Constructing All-Carbon Quaternary Stereocenters
《Chinese Journal of Chemistry》2022年第6期687-692,共6页Fan-Tao Meng Xiao-Yan Qin Jing Li Tian-Shu Zhang Shu-Jiang Tu Bo Jiang Wen-Juan Hao 
We are grateful for financial support from the National Natural Science Foundation of China(Nos.21871112 and 21971090);the Science and Technology of Xuzhou(KC21022)。
Molecular scaffolds endowed with all-carbon quaternary stereocenter are ubiquitous in natural products and significant bioactive molecules.However,efficient construction of this type of structure units is full of chal...
关键词：ALLYLATION Domino reactions CARBOCYCLES Gold self-relay catalysis 1 3-Enynes 
Fusing Carbocycles of Inequivalent Ring Size to a Bis(imino)pyridine-Iron Ethylene Polymerization Catalyst: Distinctive Effects on Activity, PE Molecular Weight, and Dispersity被引量：1
《Research》2019年第1期442-456,共15页Zheng Wang Gregory A.Solan Yanping Ma Qingbin Liu Tongling Liang Wen-Hua Sun 
This work was supported by the National Natural Science Foundation of China(No.21871275).GAS thanks the Chinese Academy of Sciences for a Visiting Fellowship.
The 4,6-bis(arylimino)-1,2,3,7,8,9,10-heptahydrocyclohepta[b]quinoline-iron(II)chlorides(aryl=2,6-Me_(2)C_(6)H_(3) Fe1;2,6-Et_(2)C_(6)H_(3) Fe_(2);2,6-i-Pr_(2)C_(6)H_(3) Fe_(3);2,4,6-Me3C_(6)H_(2) Fe4;and 2,6-Et_(2)-4...
关键词：saturated POLYMERIZATION STRAIGHT 
Synthesis of tetraphenylene derivatives and their recent advances被引量：1
《National Science Review》2017年第6期892-916,共25页Jian-Wei Han Xiao-Shui Peng Henry N.C.Wong 
supported by the National Natural Science Foundation of China(21202186,21272199 and 21472213);the Croucher Foundation(Hong Kong)in the form of a CASCroucher Foundation Joint Laboratory Grant
The synthetic strategies towards tetraphenylene derivatives are comprehensively summarized in this review.Recent advances in the functionalized tetraphenylene skeleton for research into their structurally unique prope...
关键词：tetraphenylene AROMATIC CHIRAL CARBOCYCLES eight-membered rings 
Phosphine-mediated enantioselective synthesis of carbocycles and heterocycles被引量：1
《Chinese Chemical Letters》2017年第3期493-502,共10页Yu-Ning Gao Min Shi 
financial support from the National Basic Research Program of China(973 Project,No.2015CB856603);the National Natural Science Foundation of China(Nos.20472096,21372241,21361140350,20672127,21421091,21372250,21121062,21302203,20732008 and 21572052)
Nucleophilic chiral phosphine catalysis has been prosperous in asymmetric synthesis over the past two decades. Various tunable chiral phosphines display excellent activity and selectivity in asymmetric transformations...
关键词：Bifunctional phosphines Asymmetric catalysis Carbocycles Heterocycles Cycloaddition reactions 
N-Heterocyclic Carbene-Catalyzed All Carbon-[4+2] Cyclocondensation of α,β-Unsaturated Acyl Chlorides with 3-Alkylenyloxindoles
《Chinese Journal of Chemistry》2014年第8期814-818,共5页Litao Shen Wenqiang Jia Song Ye 
Financial support from National Natural Science Foundation of China(No.21272237);the Ministry of Science and Technology of China(No.2011CB808600);the Chinese Academy of Sciences is gratefully acknowledged.
Although the NHC-catalyzed cyclization reactions have been well established for the synthesis of various heterocycles,the corresponding all carbon cyclization reaction for the synthesis of carbocycles is far less esta...
关键词：N-heterocyclic carbene catalysis CYCLOCONDENSATION spirocyclic oxindoles hexenones CARBOCYCLES 
Zirconacycle-mediated synthesis of carbocycles
《Chinese Science Bulletin》2010年第29期3235-3247,共13页CHEN Chao XI ChanJuan 
supported by the National Natural Science Foundation of China (20172032, 20872076);the Doctoral Program of Higher Education (200800030072)
Direct transformation of five-membered zirconacycles to carbocyclic compounds is of great synthetic interest.The reaction of zirconacycles with electrophiles containing at least two reactive functional groups or an ox...
关键词：碳环化合物 介导 氧化偶联反应 合成 交叉耦合 环加成 氧化剂 官能团 
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