甲苯裂解形成碳烟和PAHs的试验研究  

Formation of Soot and PAHs in Pyrolysis of Toluene

作　　者：赵鹏程 李昂[1] 李新令[1,3] 李铁 周校平 黄震[1] Zhao Pengcheng;Li Ang;Li Xinling;Li Tie;Zhou Xiaoping;Huang Zhen(Key Laboratory of Power Machinery and Engineering of Ministry of Education,Shanghai Jiao Tong University,Shanghai 200240,China;School of Naval Architecture,Ocean and Civil Engineering,Shanghai Jiao Tong University,Shanghai 200240,China;Institute of Eco-Chongming(IEC),Shanghai 202162,China)

机构地区：[1]上海交通大学动力机械与工程教育部重点实验室,上海200240 [2]上海交通大学船舶海洋与建筑工程学院,上海200240 [3]崇明生态研究院,上海202162

出　　处：《燃烧科学与技术》2022年第5期563-572,共10页Journal of Combustion Science and Technology

基　　金：国家重点研发计划资助项目(2017YFE0127100);国家自然科学基金资助项目(51576127,51976119).

摘　　要：基于流动反应器,开展了甲苯裂解过程碳烟颗粒及其前驱物多环芳烃(PAHs)的形成规律的试验研究.选取了在950~1450℃温度范围内3个不同停留时间(0.2s、0.5s、0.8s)下,甲苯裂解反应形成碳烟颗粒粒径分布特性,以及2~7环19种颗粒态PAHs的成分谱特征,进一步分析了不同裂解条件下颗粒物的当量毒性.发现甲苯裂解颗粒的生成过程伴随着凝结、凝并和团聚等气溶胶动力学变化,裂解温度越高碳烟颗粒的几何平均粒径越大、颗粒质量越高,颗粒粒径随停留时间增加向大粒子方向偏移;PAHs的浓度随温度的变化多数呈单峰分布,部分呈双峰分布,这与构成分子中的芳香环数和停留时间相关;0.5s颗粒中PAHs当量毒性高于0.8 s和0.2 s时,且峰值位于1050℃左右.Based on a flow reactor,experiments were carried out on the formation of soot particles and their pre-cursor polycyclic aromatic hydrocarbons(PAHs)in the pyrolysis of toluene.The toluene underwent oxygen-free pyrolysis within the temperature range of 950—1450℃at three different residence times,i.e.,0.2 s,0.5 s and 0.8 s.The particle size distribution and particle-bound PAHs(2—7 rings)from the toluene pyrolysis were measured.The equivalent toxicity of particle-bound PAHs was also studied.The result shows that the formation of soot particles is accompanied by aerosol kinetic changes such as condensation,coagulation and agglomeration,increase in pyrolysis temperature leads to increased geometric mean size and mass of soot particle,and particle size shifts toward larger diameter with increasing residence time.The concentration of PAHs changes with tempera-ture,most of them are of unimodal distributions and a few have a bimodal distribution,which is related to the number of aromatic rings and the length of residence time.The equivalent toxicity of particle-bound PAHs at 0.5s residence time is higher than that at 0.8 s and 0.2s,which reaches the peak at around 1050℃.

关 键 词：甲苯裂解 流动反应器 碳烟 粒径分布 PAHS 

分 类 号：TK16[动力工程及工程热物理—热能工程]