去甲咔咯的合成及其衍生化反应的进展  

Progress in the Synthesis and Derivatization of Norcorrole

作　　者：李莎 孙雅涵 蒙燕葵 李筱芳[1] 张少伟[1] Li Sha;Sun Yahan;Meng Yankui;Li Xiaofang;Zhang Shaowei(Key Laboratory of Theoretical Organic Chemistry and Functional Molecules,Ministry of Education,School of Chemistry and Chemical Engineering,Hunan University of Science and Technology,Xiangtan,Hunan 411201)

机构地区：[1]湖南科技大学化学化工学院理论有机化学与功能分子教育部重点实验室,湖南湘潭411201

出　　处：《有机化学》2022年第8期2390-2405,共16页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.22171076);湖南省科技创新计划(No.2021RC5028)资助项目。

摘　　要：近年来,去甲咔咯由于显著的顺磁环电流、高单分子电导率、狭窄的HOMO-LUMO能隙、稳定的氧化还原性能以及特有的化学反应性,引起了科研工作者的广泛关注.综述了近些年去甲咔咯的不同合成方法,重点阐述了在插入、取代、氧化还原、延伸π共轭体系四个方面的衍生化反应,同时对去甲咔咯的发展进行了展望.In recent years,norcorrole has attracted extensive attention of scientific researchers,owing to its distinct paratropic ring current,high single molecule conductivity,narrow HOMO-LUMO gap,stable redox performance and unique chemical reactivity.The different synthetic methods of norcorrole in recent years are reviewed,with emphasis on the derivatization reactions in four aspects:insertion,substitution,redox and extension ofπconjugated system,and the development of norcorrole is prospected.

关 键 词：去甲咔咯 合成 衍生化反应 反芳香性 

分 类 号：O621.25[理学—有机化学]