Catenated Cages Mediated by Enthalpic Reaction Intermediates  

作　　者：Shijun Xu Pan Li Zi-Ying Li Chunyang Yu Xiaoyun Liu Zhiqiang Liu Shaodong Zhang 

机构地区：[1]Key Laboratory of Specially Functional Polymeric Materials and Related Technology,Ministry of Education,East China University of Science and Technology,Shanghai 200237 [2]School of Chemistry and Chemical Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Key Laboratory of Electrical Insulation and Thermal Aging,Shanghai Jiao Tong University,Shanghai 200240 [3]The National and Local Joint Engineering Research Center for Biomanufacturing of Chiral Chemicals,Zhejiang University of Technology,Hangzhou 310014

出　　处：《CCS Chemistry》2021年第7期1838-1850,共13页中国化学会会刊（英文）

基　　金：supported by the National Natural Science Foundation of China(key program 21890733)and the Shanghai Natural Science Foundation(no.18ZR1420800).

摘　　要：Catenated cages are generally considered thermodynamically more stable than their constituent monomeric cages.However,the catenation mechanism is yet to be elucidated;it would require systematic investigation into the structural effects of the building blocks,their enthalpic and entropic contributions,and the effect of solvents.By inspecting these factors,we rationalized some design principles for the efficient construction of catenated cages.

关 键 词：CAGE CATENANE enthalpic intermediate interlocked cages supramolecular chemistry 

分 类 号：O62[理学—有机化学]