Self-Assembly of Crystalline Vesicles from Nonplanarπ-Conjugated Nanocycles  

作　　者：Huang Tang Zhewei Gu Chengyang Qiao Zhibo Li Wei Wu Xiqun Jiang 

机构地区：[1]MOE Key Laboratory of High Performance Polymer Materials and Technology,Department of Polymer Science and Engineering,College of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023 [2]School of Polymer Science and Engineering,Qingdao University of Science and Technology,Qingdao 266042

出　　处：《CCS Chemistry》2021年第7期1851-1861,共11页中国化学会会刊（英文）

基　　金：supported by the Natural Science Foundation of China(nos.51690153 and 21720102005);the National Key R&D Program of China(nos.2017YFA0701301 and 2017YFA0205401);the Program for Changjiang Scholars and Innovative Research Team in University.

摘　　要：There is a great demand for self-assembled carbon nanomaterials because of their importance in optoelectronics,biomaterials,and so forth.Herein,we report a novel type of self-assembled,nanoscale,crystalline vesicle from nonplanarπ-conjugated nanocycles.We designed four different structural[8]cycloparaphenylenes([8]CPPs)molecules and demonstrated that these nonplanarπ-conjugated CPP nanocycles could self-assemble into multilamellar,crystalline vesicles in tetrahydrofuran(THF)/H2O mixed solvent.

关 键 词：cycloparaphenylene VESICLE crystallization cell internalization SUPRAMOLECULE 

分 类 号：O62[理学—有机化学]