Radical–Radical Cross-Coupling Assisted N–S Bond Formation Using Alternating Current Protocol  

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作  者:Yong Yuan Jun-Chao Qi Dao-Xin Wang Ziyue Chen Hao Wan Jing-Yun Zhu Hong Yi Abhishek Dutta Chowdhury Aiwen Lei 

机构地区:[1]National Research Center for Carbohydrate Synthesis,Jiangxi Normal University,Nanchang 330022 [2]College of Chemistry and Molecular Sciences,Institute for Advanced Studies(IAS),Engineering Research Center of Organosilicon Compounds&Materials(Ministry of Education),Wuhan University,Wuhan,Hubei 430072 [3]Gansu International Scientific and Technological Cooperation Base of Water-Retention Chemical Functional Materials,College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou,Gansu 730070

出  处:《CCS Chemistry》2022年第8期2674-2685,共12页中国化学会会刊(英文)

基  金:supported by the National Natural Science Foundation of China(no.22031008)and the Science Foundation of Wuhan(no.2020010601012192).

摘  要:Alternating current(AC)electrolysis is a promising,yet challenging,and under-developed protocol in organic synthesis.To achieve as high an atomefficiency as possible and avoid the use of external oxidant,electrochemistry has become a standard organic synthesis tool.Herein,an AC-basedprotocol is a superior option than its counterpart,direct current(DC),especially for those reactions that cannot be accomplished by DC.

关 键 词:alternating current electrolysis ANILINES THIOLS cross-coupling reaction N–S bond formation 

分 类 号:O62[理学—有机化学]

 

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