the National Natural Science Foundation of China(22071097,22271307,22378432);the Guangdong Basic and Applied Basic Research Foundation(2021B1515020062);the Shenzhen Science and Technologyy Program(JCYJ20220818100804010).
Although it offers a direct route to access synthetically valuableα-chiral primary amines,asymmetric transfer hydrogenation of NH imines has been rarely studied,due in large part to the inaccessibility and instabilit...
supported by the National Natural Science Foundation of China(Nos.22061017 and 21862006);Science and technology program of Gansu Province(Nos.22YF7GG127 and 23JRRG0002);Hexi University Research Start-up Fund Project(Nos.KYQD2020013).
Single-atomic catalysts(SACs)caught considerable attention due to their unique structural properties,complete exposed active site,and 100%atom utilization efficiency with remarkable catalytic activity.Mesoporous singl...
This work was supported by the National Natural Science Foundation of China(Nos.22171284 and 21602249);the Fundamental Research Funds for the Central Universities,the Research Funds of Renmin University of China(No.20XNLG20);the Public Computing Cloud Platform,Renmin University of China.
We describe an iridium-catalyzed ortho-selective C–H borylation of unprotected anilines.The employing strongσ-donating cyclometalated mesoionic carbene as C^C bidentate ligand is crucial for the high ortho-selectivi...
The structure of Montelukast-derivatives(12)in Table 2 and the structure of its product 25 in page s24 are wrong,and they should be Montelukast-derivatives(12)methyl(R,E)-2-(1-(1-(3-(2-(7-chloroquinolin-2-yl)vinyl)phe...
supported by NSF of China(Grant 21922703 and 91953112 to H.W.);the Natural Science Foundation of Jiangsu Province(Grant BK20190004 and BK20202004);National Key R&D Program of China(2019YFA0905800).
Nitroanilines are important building blocks in pharmaceuticals,materials and dyes.Nitration methods for anilines under mild conditions are highly desired.Herein,we report a photochemical method for the nitration of an...
Scheme 1 in the article should be corrected as follows:On page 3, left column, the sentence of “The absolute configurations of the products were assigned by analogy to recovered (S)-1e,” should be revised to “The a...
supported by the National Natural Science Foundation of China(no.22031008)and the Science Foundation of Wuhan(no.2020010601012192).
Alternating current(AC)electrolysis is a promising,yet challenging,and under-developed protocol in organic synthesis.To achieve as high an atomefficiency as possible and avoid the use of external oxidant,electrochemis...
NSFC(Grant No.22171186) and ShanghaiTech University start-up funding for financial support;the support from Analytical Instrumentation Center(contract no.SPST-AIC10112914),SPST。
An efficient kinetic resolution(KR)protocol for 1,2-diamines has been developed through asymmetric electrophilic aminations of anilines enabled by chiral phosphoric acid catalysis.A wide array of substituted 1,2-diami...
the financial support of the National Natural Science Foundation of China(Grants 21977073);the Liao-ning BaiQianWan Talents Program;Liaoning Revitalization Tale nts Program;the program for the innoyative research team of the Ministry of Education;the program for the Liaoning innovative research team in university.
A gold(Ⅰ)-catalyzed 6-endo-dig cyclization of aromatic 1,5-enynes was developed to synthesize 2-(naphthalen-2-yl)anilines.The functional group tolerance of this cyclization was examined systematically and a possible ...
supported by NSF of China(no.21602064 and 22004041);the Science and Technology Project of Quanzhou City(2018C073R);the Instrumental Analysis Center of Huaqiao University.
Rhodium-catalysed regioselective redox-neutral[3+3]-cycloaddition of anilines with CF_(3)-ynones was achieved via a traceless directing group strategy.A variety of substituted 2-trifluromethylquinoline compounds were ...