金属/电催化NHPI烷基酯脱羧构筑碳-碳键研究进展  

Recent advance of(N-acyloxy)phthalimide esters decarboxylation to construct carbon-carbon bond under the catalyst of electric/metal catalysts

作　　者：梁炳玉 路博华 陶乐[1] 李玉江[1] 王清龙 董黎红[1] 郭晓河[1] 田云飞 LIANG Bingyu;LU Bohua;TAO Le;LI Yujiang;WANG Qinglong;DONG Lihong;GUO Xiaohe;TIAN Yunfei(High&New Technology Research Center of Henan Academy of Science,Zhengzhou 450002,Henan,China;Department of Science,Henan University of Animal Husbandry and Economy,Zhengzhou 450011,Henan,China;College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang 471000,Henan,China)

机构地区：[1]河南省科学院高新技术研究中心,河南郑州450002 [2]河南牧业经济学院理学部,河南郑州450011 [3]洛阳师范学院化学化工学院,河南洛阳471000

出　　处：《化学研究》2023年第1期85-94,共10页Chemical Research

基　　金：河南省自然科学基金(202300410290);河南省科学院基本科研费项目(220602011)。

摘　　要：近年来,由于自由基反应在碳-碳键构筑中独特的作用,有机化学家相继开发了各种自由基前体化合物。N-取代丁二酰亚胺(NHPI)还原活性酯作为一种重要的自由基前体化合物,近期受到了有机化学家的广泛关注。本文综述了该领域的最新研究进展,主要介绍在电、金属催化条件下,自由基诱导N-取代丁二酰亚胺酯类化合物参与的碳-碳键构筑。Recently,organic chemists continuously developed a great variety of radical precursors with the unique role of free radical reactions in the construction of carbon-carbon bonds.Especially,(N-acyloxy)phthalimide(NHPI)esters,a class of radical precursors compounds with great significance,has been widely concerned by scientists.In this perspective article,we will systematically summarize the advance in the field of the radical-induced of(N-acyloxy)phth-alimide esters to construct carbon-carbon bond according to the catalyst type,including electrochemical catalysis and metal catalysis.Meanwhile,pathways for future development have been proposed.

关 键 词：金属/电催化 N-取代丁二酰亚胺酯 碳-碳键 自由基化学 

分 类 号：O626[理学—有机化学]