Two at the price of one: kinetic resolution of multi-substituted metallocenes  

一举两得:多取代茂金属化合物的动力学拆分

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作  者:Yuanyuan Li Zhenhua Gu 李园园;顾振华(Department of Chemistry,University of Science and Technology of China,Hefei 230026,China)

机构地区:[1]Department of Chemistry,University of Science and Technology of China,Hefei 230026,China

出  处:《Science Bulletin》2022年第24期2502-2504,共3页科学通报(英文版)

基  金:supported by the National Natural Science Foundation of China(92056102)。

摘  要:Molecules containing the key planar chiral scaffold are commonly used as ligands in asymmetric catalysis [1]. As such, developing efficient methods to rapidly functionalize planar chiral scaffolds has received substantial attention, and several elegant synthetic strategies have been developed to this end. Over the past decade, transition-metal-catalyzed enantioselective C–H functionalization has become one of the most powerful strategies in the field [2].

关 键 词:动力学拆分 茂金属化合物 PLANAR 

分 类 号:O621.251[理学—有机化学]

 

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