基于红霉素选择性分离的分子印迹膜制备及其性能研究  

Preparation of Molecularly Imprinted Membranes Based on Selective Separation of Erythromycin and Research on Separation Behavior

作　　者：孙冬舒 周玉凤 程浩 SUN Dong-shu;ZHOU Yu-feng;CHENG Hao(College of Engineering,Jilin Normal University,Siping 136000,China;Deparment of Chemistry,Liaoyuan Branch of Jilin Normal University,Liaoyuan 136200,China;Students Affairs Office,Siping Vocational College,Siping 136000,China)

机构地区：[1]吉林师范大学工程学院,吉林四平136000 [2]吉林师范大学辽源分院化学系,吉林辽源136200 [3]四平职业大学学生工作处,吉林四平136000

出　　处：《南京晓庄学院学报》2022年第6期11-15,共5页Journal of Nanjing Xiaozhuang University

基　　金：国家自然科学基金项目(22004047);吉林省教育厅科学技术项目(JJKH20200427KJ).

摘　　要：以聚偏氟乙烯为基膜材料,红霉素为目标分子,利用聚乙二醇和二氧化钛粒子对其进行改性,制备出红霉素分子印迹膜(PPT-MIMs)和非印迹膜(NMIMs).并运用SEM及水接触角对PPT-MIMs进行表征,分析其表面形貌和亲水性.通过对PPT-MIMs的等温吸附、动力学吸附、选择性吸附研究,分析PPT-MIMs对红霉素和罗红霉素的特异选择性分离性能.通过循环实验证明PPT-MIMs具有较高的可重复使用性和稳定性.制备出的PPT-MIMs为复杂组分中单一物质的分离提供借鉴和指导作用.Molecularly imprinted membranes(PPT-MIMs)and non-imprinted membranes(NMIMs)were preparedby modification of polyethylene glycol and titaniumdioxide,which polyvinylidene fluoride as matrix and erythromycinas target molecules.The PPT-MIMs was systematically characterized by various means,and its surface structure and morphology were analyzed.The specific selective separation performance of PPT-MIMs to erythromycin and roxithromycin was analyzed by isothermal adsorption,kinetic adsorption and selective adsorption.The result of cycle experiment indicated that PPT-MIMs possess high stability.The prepared PPT-MIMs can provide reference and guidance for the separation of single substances in complex components.

关 键 词：膜分离技术 分子印迹膜 选择性分离 红霉素 

分 类 号：X131.2[环境科学与工程—环境科学]