基于钌配合物催化醇类化合物氧化反应研究进展  

Research Progress on the Oxidation of Alcohols Catalyzed by Ruthenium Complex

作　　者：刘冉 郝志强 韩占刚[1] 林进[1] LIU Ran;HAO Zhiqiang;HAN Zhangang;LIN Jin(College of Chemistry and Materials Science,Hebei Normal University,Hebei Shijiazhuang 050024,China)

机构地区：[1]河北师范大学化学与材料科学学院,河北石家庄050024

出　　处：《河北师范大学学报（自然科学版）》2023年第2期158-168,共11页Journal of Hebei Normal University：Natural Science

基　　金：河北省自然科学基金(B2021205007,B2019205087);河北省高等学校科学技术研究项目(ZD2022110,QN2019036);河北师范大学研发中心专项基金(L2022T01)。

摘　　要：过渡金属配合物催化醇类化合物氧化成相应的羰基化合物是制备醛酮类化合物的一种重要方法.钌配合物因其具有多重价态,催化活性高且热稳定性好而备受关注.近年来,基于钌配合物催化的醇类化合物氧化反应在有机合成中得到了快速发展,并取得了良好的研究结果.综述了近年来均相钌配合物在环境友好型氧化剂(氧气、过氧化氢等)作用下催化醇类化合物的氧化反应和脱氢反应,介绍了典型的反应机理,进一步展望了其研究前景.Transition metal complexes-catalyzed oxidation of alcohols to corresponding carbonyl compounds is an important method to prepare aldehydes and ketones.Ruthenium complexes have attracted much attention because of their multiple valence states, high catalytic activity and some thermal stability.In recent years, the oxidation of alcohols catalyzed by ruthenium complexes has developed rapidly in organic synthesis, and some research results have been obtained.The oxidation and dehydrogenation of alcohols catalyzed by homogeneous ruthenium complexes under the action of environment-friendly oxidants(oxygen, hydrogen peroxide, etc.)in recent years were reviewed.The representative mechanisms were introduced, and its research prospet was also prospected.

关 键 词：钌配合物 氧化反应 脱氢反应 羰基化合物 

分 类 号：O622.3[理学—有机化学]