Interface boosted highly efficient selective photooxidation in Bi_(3)O_(4)Br/ Bi_(2)O_(3) heterojunctions  

作　　者：Xianshun Sun Lei Li Sen Jin Wei Shao Hui Wang Xiaodong Zhang Yi Xie 

机构地区：[1]Hefei National Research Center for Physical Sciences at Microscale,University of Science and Technology of China,Hefei,Anhui 230026,PR China [2]Institute of Energy,Hefei Comprehensive National Science Center,Hefei 230031,PR China

出　　处：《eScience》2023年第2期77-82,共6页电化学与能源科学（英文）

基　　金：This work was supported by the National Key R&D Program of China(2022YFA1502903);the Strategic Priority Research Program of Chinese Academy of Sciences(XDB36000000);the National Natural Science Foundation of China(92163105,T2122004,21890754,U2032212,U2032160);the Youth Innovation Promotion Association of CAS(Y2021123);the University Synergy Innovation Program of Anhui Province(GXXT-2020-005);the Fundamental Research Funds for the Central Universities(WK2060000039,WK2060000035).We gratefully acknowledge the supercomputing system in the Supercomputing Center of University of Science and Technology of China.

摘　　要：Selective photooxidation of amines to biologically important imines is in great demand for industrial applications.The conversion efficiency and selectivity of the process are strongly dependent on the activation of photocatalytic molecular oxygen(O_(2))into reactive oxygen species.Here,we propose the construction of rich interfaces to boost photocatalytic O_(2) activation by facilitating the transfer of photocarriers.Taking Bi_(3)O_(4)Br/Bi_(2)O_(3) heterojunctions as an example,rich interfaces facilitate electron transfer to adsorbed O_(2) for superoxide(O_(2)⋅^(-))generation,thus achieving≥98%conversion efficiency and selectivity for benzylamine and benzylamine derivatives.This study offers a valid method to design advanced photocatalysts for selective oxidation reactions.

关 键 词：INTERFACE Heterojunction Superoxide radical Selective photooxidation IMINES 

分 类 号：O62[理学—有机化学]