support from the National Natural Science Foundation of China(22377113,21927811,22134004);the Taishan Scholar Program of Shandong Province(tsqn202306103);the Fundamental Research Funds for the Central Universities(Ocean University of China)is greatly appreciated.
3,3-Disubstituted oxindoles,forming the core of extensive bioactive natural products and drugs,attract tremendous efforts to develop efficient methods for their preparation.Here,a photocatalyst-free approach for the s...
The synthesis ofα-amino acid from imines with different carbonyl sources is attractive for both synthetic organic and medicinal chemistry communities.Imines,which were easily available from the corresponding ketones ...
The electrocatalytic synthesis of imines through the reductive imination of nitroarenes with aldehydes is a facile,environmentally friendly,and valuable process.In this study,high selectivity electrosynthesis of imine...
the National Natural Science Foundation of China(22071097,22271307,22378432);the Guangdong Basic and Applied Basic Research Foundation(2021B1515020062);the Shenzhen Science and Technologyy Program(JCYJ20220818100804010).
Although it offers a direct route to access synthetically valuableα-chiral primary amines,asymmetric transfer hydrogenation of NH imines has been rarely studied,due in large part to the inaccessibility and instabilit...
supported by the Opening Project of Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan (LZJ2101);the Fundamental Research Funds of China West Normal University (19D038)
Organic-inorganic MoO_(3)/PI(MoPI)composites were prepared using a simple one-pot thermal copolymerization method.The resulting composites exhibited enhanced photocatalytic activity for the selective oxidation of benz...
supported by the National Key R&D Program of China(grant no.2022YFA1504302);the National Natural Science Foundation of China(grant nos.22188101,91956000,and 92256301);the Fundamental Research Funds for the Central Universities,and the Haihe Laboratory of Sustainable Chemical Transformations.
Asymmetric hydrogenation of dialkyl imines to chiral amines is difficult because the two alkyls of imines are so similar in spatial and electronic structure that chiral catalysts are difficult to distinguish between t...
financially supported by the National Natural Science Foundation of China(Nos.22202105,22002043 and 22205113);the Natural Science Foundation of Jiangsu Province(Nos.BK20210608 and BK20210626);the Natural Science Foundation of Jiangsu Higher Education Institutions of China(Nos.21KJA150003 and 21KJB150027);the China Postdoctoral Science Foundation(No.2022M711645)。
Photocatalytic reductive amination of biomass-derived aldehydes is a desirable way to selectively upgrade biomass into value-added nitrogen-containing chemicals under mild conditions.However,it is challenging to produ...
supported by the National Natural Science Foundation of China (22071188, 21871212);the Open Foundation of CAS Key Laboratory of Molecular Recognition and Function;the “Double First-Class” Project of Shihezi University。
Ligand-mediated nickel-catalyzed asymmetric hydrogenation of alkynone imines has been achieved. By using Ni(OAc)_2·4H_2O/(S,S)-Ph-BPE complex as a catalyst, the chemo-and enantioselective hydrogenation of alkynone im...
the financial support from the National Natural Science Foundation of China (Nos. 22022102 and 22071010);the financial support from China Postdoctoral Science Foundation (No. 2021M700462)。
We report two air-stable nickel(II) half-sandwich complexes,Cp*Ni(1,2-Cy_(2)PC_(6)H_(4)O)(1) and Cp*Ni(1,2-Ph_(2)PC_(6)H4NH)(2),for cooperative B-H bond activation and their applications in catalytic hydroboration of ...
the Opening Project of Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan(Grant number:LZJ2101);the Fundamental Research Funds of China West Normal University(Grant number:19D038).
Polyimide(PI) is an organic polymer material with good stability and diverse sources that has attracted widespread attention in the field of photocatalysis. In this study, a series of PI photocatalysts were synthesize...