Anthrazoline Photocatalyst for Promoting Esterification and Etherification Reactions via Photoredox/Nickel Dual Catalysis  

作　　者：Xiaolin Zhu Qiujin Fan Wei Luo Danfeng Wang Yihui Jia Heyang Li Zhen Wang Qi Xiao Xiaoming He 

机构地区：[1]Key Laboratory of Applied Surface and Colloid Chemistry of Ministry of Education,School of Chemistry of Chemical Engineering,Shaanxi Normal University,Xi'an,Shaanxi,710119 China [2]State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering,Donghua University,Shanghai,201620 China [3]Jiangsu Key Laboratory of Fine Petrochemical Engineering,School of Petrochemical Engineering,Changzhou University,Changzhou,Jiangsu,213164 China

出　　处：《Chinese Journal of Chemistry》2023年第4期411-416,共6页中国化学（英文版）

基　　金：This work was supported by the National Natural Science Foundation of China(22202128);the Fundamental Research Funds for the Central University(GK202205016 and GK202201006);China Postdoctoral Science Foundation(2020M683417);the Natural Science Basic Research Plan in Shaanxi Province of China(2021JQ-302),and the Jiangsu Province Key Laboratory of Fine Petrochemical Engineering(KF2201).

摘　　要：Here,we demonstrate a readily prepared anthrazoline photocatalyst,which can effectively promote C—O bond formation reactions with the aid of Ni(II)complex.This methodology enables the esterification(36 examples)and etherification(8 examples)with a broad range of scope,allowing aryl and alkyl halides coupled with diverse carboxylic acids/alcohols.Our metal-free photocatalysts have a potential broad application,may serve as an alternative to some iridium and ruthenium based photocatalysts,and are of potential importance to the pharmaceutical industry.

关 键 词：Anthrazoline PHOTOCATALYSIS PHOTOREDOX CROSS-COUPLING C-O bond formation 

分 类 号：O62[理学—有机化学]