Recent advances in the catalytic production of bio-based diol 2,5-bis(hydroxymethyl)furan  

作　　者：Wenguang Zhao Feng Wang Kangyu Zhao Xianxiang Liu Xiaoting Zhu Le Yan Yuan Yin Qiong Xu Dulin Yin 

机构地区：[1]National&Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources,Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province,Hunan Normal University,Changsha 410081,China [2]Department of Chemical&Biomolecular Engineering,National University of Singapore,4 Engineering Drive 4,Singapore 117585,Singapore

出　　处：《Carbon Resources Conversion》2023年第2期116-131,共16页碳资源转化（英文）

基　　金：the financial support of the National Natural Science Foundation of China(22278121,21975070);Hunan Provincial Innovation Foundation for Postgraduate(QL20210132);the funding offered by China Scholarship Council(202106720021).

摘　　要：Biomass-derived 2,5-bis(hydroxymethyl)furan(BHMF)has received great attention and interest due to its broad application prospects in polyesters and medicine.Over the past decades,the catalytic systems including thermocatalytic,biocatalytic,electrocatalytic,and photocatalytic hydrogenation of 5-hydroxymethylfurfural(HMF)into BHMF have been developed to a great extent.To understand the present status and challenges of BHMF production,this review systematically evaluates recent findings and developments of HMF hydrogenation through various reaction systems,with an emphasis on catalyst screening,synthesis processes,and reaction mechanism.Furthermore,a few potential research trends are also proposed,in order to provide innovative ideas for further exploration of BHMF synthesis in a simpler,efficient,and economical way.

关 键 词：Biomass 5-HYDROXYMETHYLFURFURAL 2 5-Bis(hydroxymethyl)furan Hydrogenation Thermocatalysis BIOCATALYSIS Electrocatalysis Photocatalysis 

分 类 号：O62[理学—有机化学]