汝瓷釉料中两种呈色原料的矿物元素分析  

Analysis of Mineral Elements of Two Colored Raw Materials in Ru Porcelain Glaze

作　　者：王君子 王晓磊 宋召冰 侯冬岩 刁全平 吴寒[4] WANG Junzi;WANG Xiaolei;SONG Zhaobing;HOU Dongyan;DIAO Quanping;WU Han(Baofeng County Qingliang Temple Gentleman Ru Porcelain Research institute,Pingdingshan Henan 467492,China;Liaoning Key Laboratory of Development and Utilization for Natural Products Active Molecules,Anshan Liaoning 114007,China;School of Chemistry and Life Science,Anshan Normal University,Anshan Liaoning 114007,China;China Quality Supervision&Testing Center for Agricultural Deep Processing Products,Changchun Jilin 130002,China)

机构地区：[1]宝丰县清凉寺君子汝瓷研究所,河南平顶山467492 [2]辽宁省天然产物活性分子开发及利用重点实验室,辽宁鞍山114007 [3]鞍山师范学院化学与生命科学学院,辽宁鞍山114007 [4]国家农业深加工产品质量监督检验中心,吉林长春130002

出　　处：《鞍山师范学院学报》2023年第2期53-57,共5页Journal of Anshan Normal University

摘　　要：采用微波消解法处理汝瓷天青釉料两种呈色原料百化土和黄金土样品,用电感耦合等离子体质谱法(ICP-MS)对样品中23种矿物元素Ag、Al、As、Ba、Ca、Cd、Co、Cr、Cu、Fe、Hg、K、Li、Mg、Mn、Mo、Na、Ni、Pb、Se、Sr、V、Zn进行分析.23种矿物元素的相对标准偏差为0.52%~4.96%,准确度范围为90.5%~102.5%.结果表明:在汝瓷天青釉料两种呈色原料百化土和黄金土的23种矿物元素中,Al、Ca、Fe、K 4种矿物元素的质量分数很高,特别是Fe的质量分数最高;Mg、Mn、Na、Ni、Zn 5种矿物元素的质量分数较高;百化土中Al、Ca、Fe、Mg、Na 5种矿物元素的质量分数高于黄金土中这5种矿物元素的质量分数;黄金土中K、Mn、Ni、Zn 4种矿物元素的质量分数高于百化土中这4种矿物元素的质量分数.Microwave digestion method was used to process the samples of baihua soil and gold soil,two color raw materials of azure glaze for Ru porcelain.The 23 mineral elements Ag,Al,As,Ba,Ca,Cd,Co,Cr,Cu,Fe,Hg,K,Li,Mg,Mn,Mo,Na,Ni,Pb,Se,Sr,V and Zn were analyzed by inductively coupled plasma mass spectrometry(ICP-MS).The relative standard deviations of 23 mineral elements ranged from 0.52%to 4.96%,and the accuracy ranged from 90.5%to 102.5%.The results show that the mass fraction of Al,Ca,Fe and K of 23 mineral elements in Baihua soil and gold soil,two color raw materials of Ru porcelain azure glaze,is very high,especially the mass fraction of Fe is the highest.The mass fraction of Mg,Mn,Na,Ni and Zn were higher.The mass fraction of Al,Ca,Fe,Mg and Na in baihua soil is higher than that of in gold soil.The mass fraction of K,Mn,Ni and Zn in gold soil is higher than that in Baihua soil.

关 键 词：汝瓷釉料 呈色原料 百化土 黄金土 矿物元素 电感耦合等离子体质谱法 

分 类 号：TQ174.43[化学工程—陶瓷工业]