A Ni(II)-catalyzed reductive cross-coupling reaction of oxalates and thiosulfonates/selenosulfonates  被引量:1

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作  者:Ying Chen Fei Wang Bo-Xi Liu Wei-Dong Rao Shun-Yi Wang 

机构地区:[1]Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry,Chemical Engineering and Materials Science&Collaborative Innovation Center of Suzhou Nano Science and Technology,Soochow University,Suzhou 215123,China [2]Key Laboratory of Biomass-based Green Fuels and Chemicals,College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China

出  处:《Organic Chemistry Frontiers》2022年第3期731-736,共6页有机化学前沿(英文)

基  金:We gratefully acknowledge the National Natural Science Foundation of China(No.21971174,21772137);PAPD,Cyrus Tang(Zhongying)scholar and Soochow University for financial support.

摘  要:A Ni(II)-catalyzed reductive cross-coupling reaction of oxalates and thiosulfonates/selenosulfonates to synthesize benzylic sulfides/selenides under mild conditions is developed.The oxalates prepared from the corresponding alcohols are used as carbon radical precursors to participate in the reaction.

关 键 词:reaction NI(II) CATALYZED 

分 类 号:O62[理学—有机化学]

 

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