From amides to urea derivatives or carbamates with chemospecific C–C bond cleavage at room temperature  

作　　者：Cong Lv Dan Liu Tegshi Muschin Chaolumen Bai Agula Bao Yong-Sheng Bao 

机构地区：[1]College of Chemistry and Environmental Science,Inner Mongolia Key Laboratory of Green catalysis,Inner Mongolia Normal University,Hohhot,010022,China

出　　处：《Organic Chemistry Frontiers》2022年第5期1354-1363,共10页有机化学前沿（英文）

基　　金：Financial support from the National Nature Science Foundation of China(21861030);the Inner Mongolia Nature Science Foundation(2021MS02030);the Special Founded Project for Cultivating Major Project of Inner Mongolia Normal University(2020ZD02);the Innovative and Entrepreneurial Startup Supporting Program of Returned Overseas Scholars of Inner Mongolia Autonomous Region,the Collaborative Innovation Center for Water Environmental Security of Inner Mongolia Autonomous Region(XTCX003);the Science and Technology Program of Inner Mongolia Autonomous Region(2020PT0003)is acknowledged.

摘　　要：Ureas and carbamates are common motifs in pharmaceuticals,agrochemicals,biologically active com-pounds and organocatalysis applications.Herein,we report a significant advancement in this area and present a general method for copper-catalyzed chemospecific C–C bond cleavage of amides to syn-thesize urea derivatives and carbamates at room temperature.

关 键 词：TEMPERATURE CLEAVAGE BOND 

分 类 号：O62[理学—有机化学]