TEMPO-Mediated Oxidation of Primary Alcohols to Aldehydes under Visible Light and Air  

作　　者：Dongwang Liu Hongxia Zhou Xiangyong Gu Xiaoqin Shen Pixu Li 

机构地区：[1]Key Laboratory of Organic Synthesis of Jiangsu Province,College of Chemistry,Chemical Engineering,and Materials Science,Soochow University,199 RenAi Road,Suzhou,Jiangsu 215123,China

出　　处：《Chinese Journal of Chemistry》2014年第2期117-122,共6页中国化学（英文版）

基　　金：Financial support is provided by National Natural Science Foundation of China(No.21102097);the Specialized Research Fund for the Doctoral Program of Higher Education(No.20103201120006);Beijing National Laboratory for Molecular Sciences(BNLMS).

摘　　要：A homogeneous visible light photoredox TEMPO-mediated selective oxidation of primary alcohols to the corresponding carbonyl compounds was developed using molecular oxygen from air as the terminal oxidant.Ru(bpy)_(3)(PF_(6))_(2)(bpy:bipyridyl)and Ir(dtb-bpy)(ppy)_(2)(PF_(6))(dtb-bpy:4,4'-di-tert-butyl-2,2'-bipyridyl;ppy:2-phenylpyridine)were used as the sensitizers.

关 键 词：ALCOHOL ALDEHYDE PHOTOOXIDATION TEMPO molecular oxygen 

分 类 号：O64[理学—物理化学]