Carbon-bridged Tri(cyclopentadiene):Synthesis and Coordination with Ytterbium  

作　　者：Lin Sha Li Li Fugen Yuan 

机构地区：[1]School of Chemistry and Biochemistry,Suzhou University of Science and Technology,Suzhou,Jiangsu 215009,China

出　　处：《Chinese Journal of Chemistry》2014年第12期1214-1216,共3页中国化学（英文版）

摘　　要：Reaction of a mixture of 1,1-bis(cyclopentadienyl)cyclohexane and pentamethylenefulvene with metallic sodium in THF led to a mixture of cyclohexylidene-bridged bis(cyclopentadienyl)sodium and two-cyclohexylidenebridged tri(cyclopentadienyl)sodium.Reaction of the salt solutions with anhydrous YbCl_(3)in THF afforded a ytterbium complex mixed-ligated by bridged bis(cyclopentadienide)and bridged tri(cyclopentadienide).

关 键 词：cylcopentadienyl YTTERBIUM LANTHANIDE FULVENE 

分 类 号：O62[理学—有机化学]